Table 3 ANOVA for the adjusted variables to response optimization design η for stored emulsions at 20 °C and 4 °C, and hardness, cohesiveness and springiness of oleogels.
Independent factor | ηstored 20°C (mPa s) | ηstored 4°C (mPa s) | Hardness (N) | Cohesiveness | Springiness | ||||||||||
---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
SS | df | p-value | SS | df | p-value | SS | df | p-value | SS | df | p-value | SS | df | p-value | |
Model | 7.5 × 107 | 46 | 0.0015 | 1.8 × 107 | 46 | 0.045 | 2.0 × 105 | 46 | 0.006 | 1.95 | 46 | 0.023 | 2.937 | 46 | 0.003 |
A | 8.7 × 104 | 1 | 0.57 | 1.3 × 105 | 1 | 0.37 | 1.4 × 104 | 1 | 0.003 | 0.009 | 1 | 0.42 | 0.012 | 1 | 0.33 |
B | 7.2 × 105 | 1 | 0.12 | 1.7 × 104 | 1 | 0.74 | 9.3 × 102 | 1 | 0.33 | 0.09 | 1 | 0.024 | 0.111 | 1 | 0.012 |
C | 1.1 × 105 | 1 | 0.52 | 3.5 × 106 | 1 | 0.0006 | 4.5 × 104 | 1 | < 0.0001 | 0.03 | 1 | 0.19 | 0.307 | 1 | 0.0005 |
D | 4.2 × 106 | 2 | 0.007 | 7.1 × 104 | 2 | 0.79 | 2.7 × 103 | 2 | 0.27 | 0.10 | 2 | 0.05 | 0.101 | 2 | 0.045 |
F | 6.1 × 105 | 1 | 0.15 | 4.0 × 105 | 1 | 0.13 | 2.0 × 104 | 1 | 0.0008 | 0.05 | 1 | 0.07 | 0.455 | 1 | < 0.0001 |
G | 1.1 × 107 | 2 | 0.0002 | 2.2 × 106 | 2 | 0.0099 | 3.9 × 104 | 2 | 0.0002 | 0.13 | 2 | 0.03 | 0.715 | 2 | < 0.0001 |
AC | 3.0 × 106 | 1 | 0.006 | 2.4 × 104 | 1 | 0.69 | 1.9 | 1 | 0.97 | 0.06 | 1 | 0.0516 | 0.002 | 1 | 0.73 |
BC | 5.0 × 106 | 1 | 0.001 | 5.1 × 103 | 1 | 0.86 | 2.2 × 103 | 1 | 0.15 | 0.007 | 1 | 0.4709 | 0.009 | 1 | 0.40 |
BD | 4.2 × 106 | 2 | 0.007 | 9.6 × 105 | 2 | 0.08 | 5.5 × 103 | 2 | 0.09 | 0.19 | 2 | 0.0101 | 0.067 | 2 | 0.10 |
BF | 2.8 × 106 | 1 | 0.007 | 3.9 × 105 | 1 | 0.14 | 1.0 × 103 | 1 | 0.31 | 0.01 | 1 | 0.3811 | 0.002 | 1 | 0.68 |
BG | 2.3 × 105 | 2 | 0.64 | 4.2 × 105 | 2 | 0.29 | 4.8 × 103 | 2 | 0.12 | 0.20 | 2 | 0.0092 | 0.011 | 2 | 0.64 |
CD | 3.5 × 106 | 2 | 0.012 | 5.8 × 105 | 2 | 0.19 | 5.7 × 102 | 2 | 0.73 | 0.05 | 2 | 0.1846 | 0.003 | 2 | 0.88 |
CF | 2.5 × 106 | 1 | 0.010 | 1.0 × 106 | 1 | 0.02 | 4.8 × 102 | 1 | 0.48 | 0.29 | 1 | 0.0007 | 0.020 | 1 | 0.22 |
CG | 2.4 × 105 | 2 | 0.63 | 8.8 × 104 | 2 | 0.75 | 2.3 × 104 | 2 | 0.002 | 0.02 | 2 | 0.5316 | 0.081 | 2 | 0.07 |
DF | 2.2 × 106 | 2 | 0.042 | 4.4 × 105 | 2 | 0.27 | 7.5 × 102 | 2 | 0.67 | 0.002 | 2 | 0.9265 | 0.056 | 2 | 0.14 |
DG | 5.5 × 106 | 4 | 0.013 | 9.9 × 105 | 4 | 0.23 | 4.5 × 103 | 4 | 0.36 | 0.21 | 4 | 0.0311 | 0.100 | 4 | 0.15 |
EG | 2.0 × 106 | 2 | 0.05 | 4.2 × 105 | 2 | 0.29 | 7.9 × 103 | 2 | 0.04 | 0.0001 | 2 | 0.9942 | 0.020 | 2 | 0.46 |
FG | 2.7 × 106 | 2 | 0.03 | 5.2 × 105 | 2 | 0.22 | 2.9 × 103 | 2 | 0.25 | 0.01 | 2 | 0.5807 | 0.034 | 2 | 0.28 |
B2 | 2.4 × 106 | 1 | 0.01 | 6.5 × 103 | 1 | 0.83 | 6.5 × 103 | 1 | 0.02 | 0.02 | 1 | 0.1940 | 0.055 | 1 | 0.06 |
C2 | 8.5 × 106 | 1 | 0.0002 | 1.2 × 106 | 1 | 0.02 | 9.7 × 102 | 1 | 0.32 | 0.11 | 1 | 0.0149 | 0.053 | 1 | 0.06 |
Residual | 2.5 × 106 | 10 | – | 1.5 × 106 | 10 | – | 9.0 × 103 | 10 | – | 0.13 | 10 | – | 0.118 | 10 | – |
Lack of fit | 2.3 × 106 | 5 | 0.007 | 1.4 × 106 | 5 | 0.007 | 8.0 × 103 | 5 | 0.019 | 0.11 | 5 | 0.05 | 0.095 | 5 | 0.07 |
Pure Error | 1.8 × 105 | 5 | – | 1.0 × 105 | 5 | – | 9.9 × 102 | 5 | – | 0.02 | 5 | – | 0.023 | 5 | – |
R2 | 0.97 | – | – | 0.93 | – | – | 0.96 | – | – | 0.94 | – | – | 0.96 | – | – |
Adj R2 | 0.82 | – | – | 0.58 | – | – | 0.76 | – | – | 0.66 | – | – | 0.78 | – | – |