Table 4 The comparison of the activity of Pd@Per-P for the model hydrogenation reaction.
Entry | Catalyst | Solvent | H2 Pressure | Time (min) | Temp. (°C) | Yield (%) | Refs. |
|---|---|---|---|---|---|---|---|
1 | PdNP(0.5%)/Al2O3 (0.3 g) | THF | 1 atm | 180 | r.t | 100 | |
2 | Pd@Hal-Hydrogel + cyclodextrin (2 wt.%) | H2O | 1 bar | 120 | 50 | 95 | |
3 | Pd@Hal-TCT-Meta | H2O | 1 bar | 75 | 65 | 100 | |
4 | APSNP b (1 mol%) | EtOH | 40 atm | 120 | r.t | 100 | |
5 | Pd@CS-CD-MGQDsc (0.5 mol%) | H2O | 1 atm | 60 | 50 | 97 | |
6 | Pd/PPh3@FDU‐12 (8.33 × 10–4 mmol Pd) | EtOH | 10 bar | 60 | 40 | 99 | |
7 | Pd@Hal-biochard (0.03 mol%) | H2O | 1 bar | 60 | r.t | 75 | |
8 | Pd@Hal/di‐ureae (1.5 wt.%) | H2O | 1 atm | 60 | 50 | 100 | |
9 | Pd@Per-P(0.03 g) | H2O:EtOH (1:1) | 1 atm | 90 | 45 | 98 | |
10 | Pd@Hal-CCDf (1 wt.%) | H2O | 1 atm | 90 | r.t | 100 | |
11 | Pd/CNT-P | H2O:EtOH (1:1) | 1 bar | 120 | 40 | 98 | This work |
