Table 1 Possible oxidative structures of tested monoterpenes related to observed molecular ions.

From: In-situ TD-GCMS measurements of oxidative products of monoterpenes at typical vaping temperatures: implications for inhalation exposure to vaping products

Molecular ion

Formula

Change in MW

Oxidative product

Explanation

132

C10H12

M-4

− 4[H]

Loss of 4 hydrogens to form two double bonds from two –CH2–CH2− group

134

C10H14

M-2

− 2[H]

Loss of 2 hydrogens to form an double bond from –CH2–CH2

136

C10H16

M

 

Parent compound or its isomers

138

C9H14O

M + 2

 + [O] and −[CH2]

Replacing –CH2- group with an oxygen

150

C10H14O

M + 14

 + [O] and − 2[H]

Formation of C=O group from –CH2

152

C10H16O

M + 16

 + [O]

Insertion of oxygen between C and H in –CH2− CH2− group to form hydroxyl group, or addition of oxygen to a double bond to form epoxide group

154

C10H18O

M + 18

 + [O] and + 2[H]

Addition of OH and H to a double bond