Table 1 Characteristic bands of sublates obtained after the separation by sorption/precipitate flotation of U(VI) from Cr (VI), Cu(II), and Mo(VI).

From: U(VI) removal from diluted aqueous systems by sorption–flotation

Characteristic bands, cm−1

Characteristic bands attribution

References

Sample I

Sample A

Sample B

Sample C

Sample E

Sample D

Sample F

Sample G

Sample H

3609-

3305

3037

3609-

3305

3037

3609-

3305

3037

3679-

3218

3048

3692-

3246

3034 (s)

3685-

3212

3041

3685-

3233

3048

3685-

3233

3048

3678-

3240

3048 (s)

νOH non-assoc

νOH assoc

νHOH

78,79,80,81

2854

2728

2854

2728

2854

2724

2857

2729

2850

2701

2850

2723

1964

2843

2715

2347

2843

2715

2347

2850

2701

2347

νCH

80

1634

1620

1634

1632

1639

1639

1632

1639

1639

δOH, δHOH

79,81

1486*

1521

1542

1493*

1512

1335*

1518

1327*

1519 (s)

1328*

1540 (s)

1306*

1526 (s)

1328*

1512

1327*

\({\nu }_{{CO}_{3}^{2-}}\)

\({\nu }_{{COO}^{-}}^{*}\)

80,82

1000–800

957

858

903

\({\delta }_{{CO}_{3}^{2-}}\)

80,82

b682

b647

b612

a703

626

a703

c619

d683

d690

f669

d683

676

669

a, bFe-O, δFe-O)

cFe-CO in the same plane complex

[(UO2)2(OH )2]2+ + CO32−

fνCu-O, δCu-O

83,84,85

569

534

556

527

534

506

541

556

506

542

542

563

νFe-O

79,83,84

499

463

478

485

414

470

 

428

421

470

δFe-O

79,86,87,88

  1. Where : Sample I = Fe2O3·nH2O symbolized as Fe (III); Sample A = Fe(III) + U(VI); Sample B = Fe(III) + U(VI) + Cr(VI); Sample C = Fe(III) + U(VI) + Cu(II); Sample E = Fe(III) + U(VI) + Mo(VI); Sample D = Fe(III) + U(VI) + Cr(VI) + Cu(II); Sample F = Fe(III) + U(VI) + Cr(VI) + Mo(VI); Sample G = Fe(III) + U(VI) + Cu(II) + Mo(VI); Sample H = Fe(III) + U(VI) + Cr(VI) + Cu(II) + Mo(VI).