Table 1 Characteristic bands of sublates obtained after the separation by sorption/precipitate flotation of U(VI) from Cr (VI), Cu(II), and Mo(VI).
From: U(VI) removal from diluted aqueous systems by sorption–flotation
Characteristic bands, cm−1 | Characteristic bands attribution | References | ||||||||
---|---|---|---|---|---|---|---|---|---|---|
Sample I | Sample A | Sample B | Sample C | Sample E | Sample D | Sample F | Sample G | Sample H | ||
3609- 3305 3037 | 3609- 3305 3037 | 3609- 3305 3037 | 3679- 3218 3048 | 3692- 3246 3034 (s) | 3685- 3212 3041 | 3685- 3233 3048 | 3685- 3233 3048 | 3678- 3240 3048 (s) | νOH non-assoc νOH assoc νHOH | |
2854 2728 | 2854 2728 | 2854 2724 | 2857 2729 | 2850 2701 | 2850 2723 1964 | 2843 2715 2347 | 2843 2715 2347 | 2850 2701 2347 | νCH | |
1634 | 1620 | 1634 | 1632 | 1639 | 1639 | 1632 | 1639 | 1639 | δOH, δHOH | |
1486* | 1521 | 1542 1493* | 1512 1335* | 1518 1327* | 1519 (s) 1328* | 1540 (s) 1306* | 1526 (s) 1328* | 1512 1327* | \({\nu }_{{CO}_{3}^{2-}}\) \({\nu }_{{COO}^{-}}^{*}\) | |
1000–800 | – | 957 858 | 903 | – | – | – | – | – | \({\delta }_{{CO}_{3}^{2-}}\) | |
b682 b647 b612 | a703 626 | a703 c619 | d683 | d690 | f669 | d683 | 676 | 669 | a, b (νFe-O, δFe-O) cFe-CO in the same plane complex [(UO2)2(OH )2]2+ + CO32− fνCu-O, δCu-O | |
569 534 | 556 527 | 534 | 506 | 541 | 556 506 | 542 | 542 | 563 | νFe-O | |
499 463 | 478 | 485 | 414 | 470 | 428 | 421 | 470 | δFe-O |