Table 3 Molar ratios of elements identified by SEM–EDS spectroscopy for areas with archaeological residue (bitumen) and fresh areas (without the residue) on samples 1–5.
Sample 1 | ||||||
C | 0.1670 | 0.0915 | 0.3685 | 0.0856 | 0.0963 | 0.4618 |
O | 0.5920 | 0.2660 | 0.3416 | 0.6539 | 0.6815 | 0.2401 |
Si | 0.2342 | 0.1716 | 0.1407 | 0.2502 | 0.1008 | 0.0369 |
C/Si | 0.71 | 0.53 | 2.62 | 0.34 | 0.96 | 12.50 |
Si/O | 0.40 | 0.65 | 0.41 | 0.38 | 0.15 | 0.15 |
Sample 2 | ||||||
C | 0.2490 | 0.1811 | 0.7889 | 0.6534 | ||
O | 0.4804 | 0.4142 | 0.1862 | 0.3376 | ||
Si | 0,0945 | 0,1940 | 0,0142 | 0,0405 | ||
C/Si | 2.63 | 0.93 | 55.52 | 16.15 | ||
Si/O | 0.20 | 0.47 | 0.08 | 0.12 | ||
Sample 3 | ||||||
C | 0.2085 | 0.5572 | 0.1440 | 0.2053 | 0.4126 | 0.4370 |
O | 0.5585 | 0.3277 | 0.6252 | 0.5131 | 0.3224 | 0.2816 |
Si | 0.2330 | 0.1113 | 0.2241 | 0.0880 | 0.1215 | 0.0237 |
C/Si | 0.89 | 5.01 | 0.64 | 2.33 | 3.39 | 18.41 |
Si/O | 0.42 | 0.34 | 0.36 | 0.17 | 0.38 | 0.08 |
Sample 4 | ||||||
C | 0.2019 | 0.1372 | 0.4178 | 0.2144 | 0.1993 | 0.3195 |
O | 0.5721 | 0.6227 | 0.2742 | 0.5628 | 0.5798 | 0.4582 |
Si | 0.2115 | 0.2253 | 0.0867 | 0.1050 | 0.1025 | 0.0199 |
C/Si | 0.95 | 0.61 | 4.82 | 2.04 | 1.94 | 16.04 |
Si/O | 0.37 | 0.36 | 0.32 | 0.19 | 0.18 | 0.04 |
Sample 5 | ||||||
C | 0.1694 | 0.1955 | 0.5404 | |||
O | 0.6408 | 0.5928 | 0.3958 | |||
Si | 0.1705 | 0.1020 | 0.0381 | |||
C/Si | 0.99 | 1.92 | 14.17 | |||
Si/O | 0.27 | 0.17 | 0.10 |