Table 1 Summary of headspace volatiles emitted (in ng h−1 g−1 grain) from grain that was uninoculated (P. ctrl), surface sanitized with UV-radiation for 10-min (UV-grain), or inoculated with A. flavus or Fusarium spp. for periods of 3 h using a push headspace collection system.

From: Attraction, mobility, and preference by Lasioderma serricorne (Coleoptera: Ptinidae) to microbially-mediated volatile emissions by two species of fungi in stored grain

Compound

RT

P. ctrl

UV-grain

A. flavus-grain

Fusarium-grain

Mean ± SE

% of Total

Mean ± SE

% of Total

Mean ± SE

% of Total

Mean ± SE

% of Total

4-Ethylbenzamide

4.26

0.00 ± 0.00

0

0.00 ± 0.00

0

0.00 ± 0.00

0

0.17 ± 0.11

6

cis-1-Butyl-2-methylcyclopropane

4.38

0.10 ± 0.06

18

0.03 ± 0.01

4

0.04 ± 0.02

6

0.01 ± 0.02

0

3-Octene, (E)a

4.38

0.00 ± 0.00

0

0.02 ± 0.01

3

0.02 ± 0.02

3

0.00 ± 0.00

0

4-Heptanonea

4.45

0.01 ± 0.01

2

0.02 ± 0.01

2

0.01 ± 0.01

2

0.03 ± 0.04

1

Octanea

4.46

0.00 ± 0.00

0

0.00 ± 0.00

0

0.02 ± 0.03

3

0.05 ± 0.07

2

2,4-Dimethyl-1-heptene

4.91

0.01 ± 0.01

3

0.05 ± 0.02

7

0.02 ± 0.02

4

0.03 ± 0.03

1

2-Pentanone, 4-hydroxy-4-methyl

4.92

0.03 ± 0.02

6

0.05 ± 0.04

6

0.03 ± 0.04

5

0.00 ± 0.00

0

3-Hexanone, 2-methyla

5.26

0.00 ± 0.00

0

0.00 ± 0.00

0

0.00 ± 0.00

0

0.03 ± 0.04

1

Pyrazole-1-methanol

5.63

0.00 ± 0.00

0

0.03 ± 0.02

3

0.01 ± 0.01

1

0.00 ± 0.00

0

Mesitylenea

6.62

0.00 ± 0.00

0

0.00 ± 0.00

0

0.00 ± 0.00

0

0.06 ± 0.07

2

Pentane, 2,2,3,3-tetramethyl

7.09

0.03 ± 0.01

6

0.06 ± 0.02

8

0.02 ± 0.02

4

0.04 ± 0.03

1

Octane, 3,4,5,6-tetramethyl

7.15

0.04 ± 0.01

7

0.03 ± 0.01

4

0.05 ± 0.03

9

0.13 ± 0.13

4

Hexanoic acid, 2-ethyl-, methyl ester

7.57

0.00 ± 0.00

0

0.00 ± 0.00

0

0.00 ± 0.00

0

0.12 ± 0.06

4

Ether, hexyl pentyl

7.89

0.00 ± 0.00

0

0.01 ± 0.01

1

0.01 ± 0.01

1

0.00 ± 0.00

0

3-Hydroxy-3-methylvaleric acid

7.89

0.01 ± 0.01

2

0.00 ± 0.00

0

0.00 ± 0.00

0

0.06 ± 0.05

2

Benzene, 1,4-diethyl

7.89

0.00 ± 0.00

0

0.01 ± 0.01

2

0.00 ± 0.00

0

0.00 ± 0.00

0

Phenol, 3,4,5-trimethyl

8.13

0.00 ± 0.00

0

0.01 ± 0.01

2

0.01 ± 0.01

1

0.15 ± 0.05

5

Ethanol, 2-(octyloxy)

8.14

0.01 ± 0.01

1

0.00 ± 0.00

0

0.01 ± 0.01

1

0.00 ± 0.00

0

1-Undecene, 7-methyla

8.20

0.00 ± 0.00

0

0.01 ± 0.01

1

0.02 ± 0.01

3

0.00 ± 0.00

0

1-Dodecanola

8.21

0.00 ± 0.00

0

0.01 ± 0.01

1

0.01 ± 0.01

2

0.00 ± 0.00

0

Undecanea

8.41

0.04 ± 0.03

7

0.03 ± 0.03

4

0.02 ± 0.03

3

0.01 ± 0.01

0

Nonanala

8.51

0.06 ± 0.04

11

0.06 ± 0.05

7

0.03 ± 0.03

5

0.00 ± 0.00

0

Cyclopropanecarboxylic acid

8.52

0.00 ± 0.00

0

0.00 ± 0.00

0

0.02 ± 0.03

3

0.25 ± 0.26

8

5-Methylthiopyridin-2-ol

9.17

0.04 ± 0.03

8

0.03 ± 0.02

4

0.00 ± 0.00

0

0.03 ± 0.04

1

1-Hexanol, 5-methyl-2-(1-methylethyl)

10.54

0.00 ± 0.00

0

0.00 ± 0.00

0

0.00 ± 0.01

1

0.00 ± 0.00

0

4-Phenyl-2-butanola

10.65

0.00 ± 0.00

0

0.03 ± 0.03

3

0.00 ± 0.00

0

0.00 ± 0.00

0

Benzene, 1,3-bis(1,1-dimethylethyl)-

10.78

0.09 ± 0.03

16

0.16 ± 0.05

20

0.13 ± 0.04

22

0.11 ± 0.06

4

Ethanone, 1-(4-ethylphenyl)-

10.96

0.00 ± 0.00

0

0.00 ± 0.00

0

0.00 ± 0.00

0

0.00 ± 0.00

0

Butanoic acid, 2-(1-Propenyl)-6-methylphenol-

11.04

0.00 ± 0.00

0

0.00 ± 0.00

0

0.02 ± 0.02

4

0.00 ± 0.00

0

m-Ethylacetophenone-a

11.25

0.00 ± 0.00

0

0.08 ± 0.07

10

0.00 ± 0.00

0

0.00 ± 0.00

0

2,3,6-Trimethylhept-3-en-1-ol -

11.54

0.00 ± 0.00

0

0.00 ± 0.00

0

0.01 ± 0.01

2

0.00 ± 0.00

0

Ketone, methyl 2,2,3-trimethylcyclopentyl

11.66

0.00 ± 0.00

0

0.00 ± 0.00

1

0.01 ± 0.01

1

0.00 ± 0.00

0

Dodecane, 4-methyl-

11.67

0.02 ± 0.01

3

0.00 ± 0.00

0

0.01 ± 0.01

2

0.00 ± 0.00

0

Benzene, 4-ethyl-1,2-dimethoxy-

11.68

0.00 ± 0.00

0

0.00 ± 0.00

0

0.00 ± 0.00

0

0.49 ± 0.31

16

.alpha.-Cubebene

13.22

0.00 ± 0.00

0

0.00 ± 0.00

0

0.00 ± 0.00

0

0.08 ± 0.05

3

Germacrene D

13.37

0.00 ± 0.00

0

0.00 ± 0.00

0

0.00 ± 0.00

0

0.16 ± 0.08

5

(1R,4S,5S)-1,8-Dimethyl-4-(prop-1-en-2-yl)spiro[4.5]dec-7-ene

13.82

0.00 ± 0.00

0

0.00 ± 0.00

0

0.00 ± 0.00

0

0.40 ± 0.15

13

Di-epi-.alpha.-cedrene

15.89

0.00 ± 0.00

0

0.00 ± 0.00

0

0.00 ± 0.00

0

0.35 ± 0.17

12

Benzimidazole, 2-ethyl-1-propyl-

18.42

0.00 ± 0.00

0

0.00 ± 0.00

0

0.00 ± 0.00

0

0.03 ± 0.02

1

Hexanedioic acid, bis(2-ethylhexyl) ester

23.11

0.04 ± 0.04

7

0.03 ± 0.03

4

0.03 ± 0.05

5

0.11 ± 0.12

4

Total emissions (ng per h per g grain)

0.6 ± 0.01

100

0.8 ± 0.01

100

0.58 ± 0.01

100

3.0 ± 0.05

100

  1. There were n = 7 replicates per treatment, and mean emission rates per compound are portrayed.
  2. aCompound identity confirmed by co-injecting technical standard onto same column.