Table 1 Summary of headspace volatiles emitted (in ng h−1 g−1 grain) from grain that was uninoculated (P. ctrl), surface sanitized with UV-radiation for 10-min (UV-grain), or inoculated with A. flavus or Fusarium spp. for periods of 3 h using a push headspace collection system.
Compound | RT | P. ctrl | UV-grain | A. flavus-grain | Fusarium-grain | ||||
---|---|---|---|---|---|---|---|---|---|
Mean ± SE | % of Total | Mean ± SE | % of Total | Mean ± SE | % of Total | Mean ± SE | % of Total | ||
4-Ethylbenzamide | 4.26 | 0.00 ± 0.00 | 0 | 0.00 ± 0.00 | 0 | 0.00 ± 0.00 | 0 | 0.17 ± 0.11 | 6 |
cis-1-Butyl-2-methylcyclopropane | 4.38 | 0.10 ± 0.06 | 18 | 0.03 ± 0.01 | 4 | 0.04 ± 0.02 | 6 | 0.01 ± 0.02 | 0 |
3-Octene, (E)a | 4.38 | 0.00 ± 0.00 | 0 | 0.02 ± 0.01 | 3 | 0.02 ± 0.02 | 3 | 0.00 ± 0.00 | 0 |
4-Heptanonea | 4.45 | 0.01 ± 0.01 | 2 | 0.02 ± 0.01 | 2 | 0.01 ± 0.01 | 2 | 0.03 ± 0.04 | 1 |
Octanea | 4.46 | 0.00 ± 0.00 | 0 | 0.00 ± 0.00 | 0 | 0.02 ± 0.03 | 3 | 0.05 ± 0.07 | 2 |
2,4-Dimethyl-1-heptene | 4.91 | 0.01 ± 0.01 | 3 | 0.05 ± 0.02 | 7 | 0.02 ± 0.02 | 4 | 0.03 ± 0.03 | 1 |
2-Pentanone, 4-hydroxy-4-methyl | 4.92 | 0.03 ± 0.02 | 6 | 0.05 ± 0.04 | 6 | 0.03 ± 0.04 | 5 | 0.00 ± 0.00 | 0 |
3-Hexanone, 2-methyla | 5.26 | 0.00 ± 0.00 | 0 | 0.00 ± 0.00 | 0 | 0.00 ± 0.00 | 0 | 0.03 ± 0.04 | 1 |
Pyrazole-1-methanol | 5.63 | 0.00 ± 0.00 | 0 | 0.03 ± 0.02 | 3 | 0.01 ± 0.01 | 1 | 0.00 ± 0.00 | 0 |
Mesitylenea | 6.62 | 0.00 ± 0.00 | 0 | 0.00 ± 0.00 | 0 | 0.00 ± 0.00 | 0 | 0.06 ± 0.07 | 2 |
Pentane, 2,2,3,3-tetramethyl | 7.09 | 0.03 ± 0.01 | 6 | 0.06 ± 0.02 | 8 | 0.02 ± 0.02 | 4 | 0.04 ± 0.03 | 1 |
Octane, 3,4,5,6-tetramethyl | 7.15 | 0.04 ± 0.01 | 7 | 0.03 ± 0.01 | 4 | 0.05 ± 0.03 | 9 | 0.13 ± 0.13 | 4 |
Hexanoic acid, 2-ethyl-, methyl ester | 7.57 | 0.00 ± 0.00 | 0 | 0.00 ± 0.00 | 0 | 0.00 ± 0.00 | 0 | 0.12 ± 0.06 | 4 |
Ether, hexyl pentyl | 7.89 | 0.00 ± 0.00 | 0 | 0.01 ± 0.01 | 1 | 0.01 ± 0.01 | 1 | 0.00 ± 0.00 | 0 |
3-Hydroxy-3-methylvaleric acid | 7.89 | 0.01 ± 0.01 | 2 | 0.00 ± 0.00 | 0 | 0.00 ± 0.00 | 0 | 0.06 ± 0.05 | 2 |
Benzene, 1,4-diethyl | 7.89 | 0.00 ± 0.00 | 0 | 0.01 ± 0.01 | 2 | 0.00 ± 0.00 | 0 | 0.00 ± 0.00 | 0 |
Phenol, 3,4,5-trimethyl | 8.13 | 0.00 ± 0.00 | 0 | 0.01 ± 0.01 | 2 | 0.01 ± 0.01 | 1 | 0.15 ± 0.05 | 5 |
Ethanol, 2-(octyloxy) | 8.14 | 0.01 ± 0.01 | 1 | 0.00 ± 0.00 | 0 | 0.01 ± 0.01 | 1 | 0.00 ± 0.00 | 0 |
1-Undecene, 7-methyla | 8.20 | 0.00 ± 0.00 | 0 | 0.01 ± 0.01 | 1 | 0.02 ± 0.01 | 3 | 0.00 ± 0.00 | 0 |
1-Dodecanola | 8.21 | 0.00 ± 0.00 | 0 | 0.01 ± 0.01 | 1 | 0.01 ± 0.01 | 2 | 0.00 ± 0.00 | 0 |
Undecanea | 8.41 | 0.04 ± 0.03 | 7 | 0.03 ± 0.03 | 4 | 0.02 ± 0.03 | 3 | 0.01 ± 0.01 | 0 |
Nonanala | 8.51 | 0.06 ± 0.04 | 11 | 0.06 ± 0.05 | 7 | 0.03 ± 0.03 | 5 | 0.00 ± 0.00 | 0 |
Cyclopropanecarboxylic acid | 8.52 | 0.00 ± 0.00 | 0 | 0.00 ± 0.00 | 0 | 0.02 ± 0.03 | 3 | 0.25 ± 0.26 | 8 |
5-Methylthiopyridin-2-ol | 9.17 | 0.04 ± 0.03 | 8 | 0.03 ± 0.02 | 4 | 0.00 ± 0.00 | 0 | 0.03 ± 0.04 | 1 |
1-Hexanol, 5-methyl-2-(1-methylethyl) | 10.54 | 0.00 ± 0.00 | 0 | 0.00 ± 0.00 | 0 | 0.00 ± 0.01 | 1 | 0.00 ± 0.00 | 0 |
4-Phenyl-2-butanola | 10.65 | 0.00 ± 0.00 | 0 | 0.03 ± 0.03 | 3 | 0.00 ± 0.00 | 0 | 0.00 ± 0.00 | 0 |
Benzene, 1,3-bis(1,1-dimethylethyl)- | 10.78 | 0.09 ± 0.03 | 16 | 0.16 ± 0.05 | 20 | 0.13 ± 0.04 | 22 | 0.11 ± 0.06 | 4 |
Ethanone, 1-(4-ethylphenyl)- | 10.96 | 0.00 ± 0.00 | 0 | 0.00 ± 0.00 | 0 | 0.00 ± 0.00 | 0 | 0.00 ± 0.00 | 0 |
Butanoic acid, 2-(1-Propenyl)-6-methylphenol- | 11.04 | 0.00 ± 0.00 | 0 | 0.00 ± 0.00 | 0 | 0.02 ± 0.02 | 4 | 0.00 ± 0.00 | 0 |
m-Ethylacetophenone-a | 11.25 | 0.00 ± 0.00 | 0 | 0.08 ± 0.07 | 10 | 0.00 ± 0.00 | 0 | 0.00 ± 0.00 | 0 |
2,3,6-Trimethylhept-3-en-1-ol - | 11.54 | 0.00 ± 0.00 | 0 | 0.00 ± 0.00 | 0 | 0.01 ± 0.01 | 2 | 0.00 ± 0.00 | 0 |
Ketone, methyl 2,2,3-trimethylcyclopentyl | 11.66 | 0.00 ± 0.00 | 0 | 0.00 ± 0.00 | 1 | 0.01 ± 0.01 | 1 | 0.00 ± 0.00 | 0 |
Dodecane, 4-methyl- | 11.67 | 0.02 ± 0.01 | 3 | 0.00 ± 0.00 | 0 | 0.01 ± 0.01 | 2 | 0.00 ± 0.00 | 0 |
Benzene, 4-ethyl-1,2-dimethoxy- | 11.68 | 0.00 ± 0.00 | 0 | 0.00 ± 0.00 | 0 | 0.00 ± 0.00 | 0 | 0.49 ± 0.31 | 16 |
.alpha.-Cubebene | 13.22 | 0.00 ± 0.00 | 0 | 0.00 ± 0.00 | 0 | 0.00 ± 0.00 | 0 | 0.08 ± 0.05 | 3 |
Germacrene D | 13.37 | 0.00 ± 0.00 | 0 | 0.00 ± 0.00 | 0 | 0.00 ± 0.00 | 0 | 0.16 ± 0.08 | 5 |
(1R,4S,5S)-1,8-Dimethyl-4-(prop-1-en-2-yl)spiro[4.5]dec-7-ene | 13.82 | 0.00 ± 0.00 | 0 | 0.00 ± 0.00 | 0 | 0.00 ± 0.00 | 0 | 0.40 ± 0.15 | 13 |
Di-epi-.alpha.-cedrene | 15.89 | 0.00 ± 0.00 | 0 | 0.00 ± 0.00 | 0 | 0.00 ± 0.00 | 0 | 0.35 ± 0.17 | 12 |
Benzimidazole, 2-ethyl-1-propyl- | 18.42 | 0.00 ± 0.00 | 0 | 0.00 ± 0.00 | 0 | 0.00 ± 0.00 | 0 | 0.03 ± 0.02 | 1 |
Hexanedioic acid, bis(2-ethylhexyl) ester | 23.11 | 0.04 ± 0.04 | 7 | 0.03 ± 0.03 | 4 | 0.03 ± 0.05 | 5 | 0.11 ± 0.12 | 4 |
Total emissions (ng per h per g grain) | 0.6 ± 0.01 | 100 | 0.8 ± 0.01 | 100 | 0.58 ± 0.01 | 100 | 3.0 ± 0.05 | 100 |