Table 3 PFOM and PSOM results of AB86 dye absorption [C0 (25–200 mg/L) by CAH doses (1.5–9.0 g/L), and Temp. (25 ± 2 °C)].
From: Thermodynamic, kinetic, and isotherm studies of Direct Blue 86 dye absorption by cellulose hydrogel
Parameter | PFOM | PSOM | |||||||
---|---|---|---|---|---|---|---|---|---|
CAH (g/L) | DB86 dye (mg/L) | qe (exp.) | qe (calc.) | k1 × 103 | R2 | qe (calc.) | k2 × 103 | h | R2 |
1.5 | 25 | 5.44 | 1.96 | 15.20 | 0.916 | 5.52 | 28.64 | 0.87 | 0.996 |
50 | 3.56 | 1.89 | 16.35 | 0.855 | 10.71 | 41.52 | 4.76 | 1.000 | |
75 | 2.82 | 4.59 | 21.65 | 0.953 | 14.37 | 15.56 | 3.21 | 0.999 | |
100 | 2.27 | 5.34 | 21.65 | 0.988 | 17.24 | 13.09 | 3.89 | 0.999 | |
150 | 1.95 | 8.63 | 28.33 | 0.744 | 24.15 | 12.60 | 7.35 | 0.999 | |
200 | 1.69 | 10.38 | 14.28 | 0.841 | 27.55 | 5.79 | 4.39 | 0.994 | |
3.0 | 25 | 10.72 | 1.36 | 19.81 | 0.934 | 3.60 | 48.81 | 0.63 | 0.997 |
50 | 6.21 | 2.95 | 26.95 | 0.858 | 6.26 | 30.68 | 1.20 | 0.998 | |
75 | 5.18 | 4.51 | 30.63 | 0.824 | 9.42 | 22.40 | 1.99 | 0.999 | |
100 | 4.32 | 4.67 | 18.42 | 0.883 | 11.99 | 13.59 | 1.95 | 0.996 | |
150 | 3.75 | 5.62 | 21.42 | 0.920 | 16.50 | 10.78 | 2.94 | 0.996 | |
200 | 3.16 | 6.62 | 31.32 | 0.927 | 21.88 | 15.76 | 7.55 | 1.000 | |
4.5 | 25 | 14.21 | 1.23 | 24.87 | 0.974 | 2.88 | 58.60 | 0.49 | 0.998 |
50 | 9.31 | 2.60 | 32.93 | 0.776 | 5.23 | 44.02 | 1.20 | 0.999 | |
75 | 7.01 | 2.31 | 21.19 | 0.960 | 7.10 | 30.90 | 1.56 | 0.999 | |
100 | 5.44 | 3.60 | 23.26 | 0.895 | 9.79 | 21.03 | 2.02 | 0.998 | |
150 | 5.46 | 5.95 | 30.63 | 0.866 | 13.61 | 16.79 | 3.11 | 0.999 | |
200 | 4.79 | 4.76 | 16.12 | 0.972 | 16.16 | 13.83 | 3.61 | 0.999 | |
6.0 | 25 | 17.03 | 1.22 | 30.86 | 0.838 | 2.33 | 67.30 | 0.36 | 0.999 |
50 | 11.92 | 1.34 | 24.18 | 0.990 | 4.38 | 61.37 | 1.18 | 1.000 | |
75 | 9.69 | 1.77 | 28.79 | 0.930 | 5.49 | 58.29 | 1.76 | 1.000 | |
100 | 8.28 | 2.80 | 17.27 | 0.984 | 8.34 | 22.93 | 1.59 | 0.998 | |
150 | 7.17 | 3.60 | 19.58 | 0.993 | 11.07 | 19.05 | 2.34 | 0.999 | |
200 | 6.36 | 6.25 | 28.56 | 0.802 | 13.19 | 15.26 | 2.66 | 0.998 | |
7.5 | 25 | 24.21 | 1.04 | 29.94 | 0.906 | 1.99 | 87.56 | 0.35 | 0.999 |
50 | 16.23 | 1.06 | 22.57 | 0.973 | 3.81 | 72.44 | 1.05 | 0.999 | |
75 | 13.44 | 1.72 | 18.19 | 0.973 | 5.50 | 40.04 | 1.21 | 0.999 | |
100 | 10.95 | 3.65 | 32.24 | 0.760 | 7.22 | 29.89 | 1.56 | 0.999 | |
150 | 9.61 | 3.04 | 18.19 | 0.983 | 9.69 | 22.42 | 2.10 | 0.999 | |
200 | 8.56 | 4.05 | 17.73 | 0.960 | 13.05 | 16.66 | 2.84 | 0.998 | |
9.0 | 25 | 27.79 | 0.56 | 26.02 | 0.968 | 1.72 | 149.22 | 0.44 | 1.000 |
50 | 21.64 | 0.96 | 21.42 | 0.909 | 3.19 | 124.11 | 1.26 | 1.000 | |
75 | 16.10 | 1.47 | 16.81 | 0.941 | 4.80 | 45.92 | 1.06 | 0.998 | |
100 | 13.12 | 2.95 | 3.16 | 0.803 | 6.42 | 35.49 | 1.46 | 0.999 | |
150 | 12.99 | 3.89 | 28.10 | 0.849 | 8.64 | 24.21 | 1.81 | 0.999 | |
200 | 11.37 | 8.61 | 34.78 | 0.742 | 11.36 | 22.68 | 2.93 | 0.998 |