Table 6 Comparison results of Sm-bis(PYT)@boehmite with other catalysts for the synthesis of 5-phenyl-1H-tetrazole.

From: A new samarium complex of 1,3-bis(pyridin-3-ylmethyl)thiourea on boehmite nanoparticles as a practical and recyclable nanocatalyst for the selective synthesis of tetrazoles

Entry

Catalyst

Reaction conditions

Time (h)

Yield (%)

Refs.

1

CoY Zeolite

DMF, 120 °C

14

90

96

2

MCM-41@Cu

H2O, 80 °C

0.75

68

97

3

Cu–Zn alloy nanopowder

DMF, 135 °C

10

95

94

4

B(C6F5)3

DMF, 120 °C

8

94

98

5

Fe3O4@SiO2/Salen Cu(II)

DMF, 120 °C

7

90

99

6

Fe3O4/ZnS HNSs

DMF, 120 °C

24

81.1

100

7

Mesoporous ZnS

DMF, 120 °C

36

86

101

8

AgNO3

DMF, 120 °C

5

92

102

9

CuFe2O4

DMF, 120 °C

12

82

103

10

Nano ZnO/Co3O4

DMF, 130 °C

12

90

104

11

Cu-TBA@biochar

PEG-400, 130 °C

7

98

73

12

l-Cysteine-Pd@MCM-41

PEG-400, 100 °C

3

98

78

13

Ni-MP(AMP)2@Fe-biochar

PEG-400, 120 °C

4

92

62

14

Cu(II)-Adenine-MCM-41

PEG-400, 130 °C

5

92

105

15

Pd‐Arg@boehmite

PEG-400, 120 °C

7

97

60

16

ZrO-SB-APT@MCM-41

PEG-400, 120 °C

2

86

106

17

Cu-DABP@Fe3O4/MCM-41

PEG-400, 130 °C

2

99

107

18

Sm-bis(PYT)@boehmite

PEG-400, 120 °C

1.5

96

This work