Table 2 Metabolites identified by LCMS from G. bancanus extracts in n-hexane; dichloromethane; ethyl acetate; methanol, and essential oil.

Flavanoid

1

7.34

3-Flavanol

1.07

1.15

1.05

0.70

1.32

2

9.10

3-Hydroxy-4-methoxyflavone

1.49

1.61

1.47

–

1.84

3

10.27

Luteolin

1.79

1.93

–

–

2.22

4

10.32

Kaempferol

3.17

3.41

3.11

–

3.91

5

10.50

Catechin

2.35

2.53

2.31

–

2.90

6

11.43

Quercetin

2.58

2.78

2.53

–

3.19

7

21.39

Vitexin

0.89

0.97

0.88

–

1.11

8

22.62

Kaempferol-3-O-D-glucoside

1.24

1.34

–

–

–

9

22.63

Luteolin-7-glucoside

0.93

1.01

–

–

–

10

25.85

Isorhamnetin–3-O-b-D-galactopryranoside

1.24

1.34

–

–

–

11

30.87

Kaempferol-3-(6"-malonylglucoside)

2.54

2.73

–

–

–

12

31.82

Quercetin-3-O-malonylglucoside

2.82

3.04

–

–

–

13

33.43

Procyanidin A1

2.21

2.38

–

–

–

14

33.43

Procyanidin A2

2.63

2.84

–

–

–

15

33.50

Procyanidin B1

2.03

2.19

–

–

–

16

33.50

Procyanidin B2

1.77

1.91

–

–

–

17

35.51

Quercetin-3-glucoside-7-rhamnoside

3.05

3.29

–

–

–

18

35.52

Rutin

2.43

2.62

–

–

–

Total flavonoids

36.25

39.06

11.35

0.70

16.49

Phenyl propanoid

19

1.58

Cinnamic acid

1.07

1.16

–

–

1.32

20

2.65

Safrole

–

0.56

1.39

1.70

1.51

21

2.65

p-Coumaric acid

0.61

0.65

–

–

–

22

4.64

Caffeic acid

2.08

2.24

–

–

2.57

23

5.04

Ferulic acid

1.24

1.34

–

–

1.53

24

7.03

Sinapic acid

0.65

0.71

–

–

–

25

11.62

3-p-Coumaryl-1,5-quinolactone

1.87

2.02

1.84

–

1.22

26

11.63

3-Caffeoyl-1,5-quinolactone

1.11

1.19

1.09

–

–

27

12.05

p-Coumaroylquinic acid

0.98

1.06

0.97

–

–

28

12.15

3-Feruloyl-1,5-quinolactone

0.81

0.87

0.79

–

–

29

12.42

Chlorogenic acid

1.78

1.92

–

–

2.20

30

12.44

Quinic acid-4-O-caffeate

1.24

1.34

1.22

–

–

31

12.72

3-O-Feruloylquinic acid

2.16

2.33

2.13

–

2.67

Total phenyl propanoids

15.62

17.39

9.42

1.70

13.03

Terpenoid

32

1.03

Isoprene

–

0.13

0.31

0.38

0.34

33

1.47

p-Cymene

–

0.13

0.32

0.39

0.35

34

1.48

α-Terpinene

–

–

1.19

1.45

1.29

35

1.48

α-Pinene

–

–

1.73

2.12

0.68

36

1.48

b-Pinene

–

0.48

–

1.44

1.29

37

1.48

Sabinene

–

0.64

1.58

1.93

1.72

38

1.49

Limonene

–

1.32

3.28

4.00

3.57

39

1.49

α-Terpinolene

–

0.33

0.82

1.00

1.02

40

1.50

b-Phellandrene

–

0.99

2.45

3.00

2.67

41

1.50

b-Myrcene

–

0.71

1.76

2.15

1.92

42

1.52

g-Terpinene

–

0.76

–

2.31

2.06

43

1.64

Linalool

–

1.37

3.39

4.14

3.70

44

1.65

Isoborneol

–

0.85

2.10

2.56

2.29

45

1.66

cis-Rose oxide

–

1.04

2.57

3.14

2.80

46

1.71

Geranial

–

–

–

–

1.34

47

1.76

p-Menthadiene

–

0.41

1.00

1.23

1.10

48

1.79

Isomenthol

–

1.45

3.58

4.38

3.90

49

1.80

Neoisomenthol

–

–

0.97

1.19

1.15

50

2.82

a-Calcorene

–

0.15

–

0.44

–

51

5.48

α-Cubebene

–

0.33

–

1.00

0.56

52

5.49

α-Copaene

–

0.61

1.50

1.84

1.64

53

5.49

Longifolene

–

0.61

1.50

1.84

–

54

5.50

b-Chamigrene

–

0.15

0.37

0.46

0.41

55

5.50

b-Selinene

–

0.43

1.08

1.32

1.18

56

5.50

b -Bisabolene

–

0.13

0.32

0.39

0.35

57

5.50

b -Elemene

–

0.21

0.52

0.63

0.65

58

5.51

a-Humulene

–

0.25

0.62

0.76

0.68

59

5.51

a -Muurolene

–

–

–

0.44

0.39

60

5.52

(E,E)-a-Farnesene

–

0.49

1.20

1.47

1.31

61

5.53

a-Bourbonene

–

0.94

2.33

2.84

2.54

62

5.54

Allo-aromadendrene

–

0.72

1.78

2.18

1.94

63

5.55

a-Cadinene

–

0.65

1.61

1.96

1.75

64

5.55

a-Ylangene

–

0.49

1.20

1.47

0.87

65

5.56

Bicyclo-germacrene

–

0.41

1.00

1.23

1.53

66

5.57

g-Cadinene

–

0.30

0.75

0.92

0.82

67

5.60

g-Muurolene

–

0.47

1.18

1.44

1.28

68

5.99

Selina-4,11-diene

–

0.63

1.55

1.89

1.69

69

6.41

11-Selina-4-a-ol

–

–

0.52

0.63

0.56

70

6.95

τ-Cadinol

–

0.28

0.70

0.86

–

71

6.95

Nerolidol

–

–

0.95

1.16

1.03

72

6.97

Farnesol

–

0.49

1.20

1.47

1.31

73

6.97

10-Epi-g-eudesmol

–

0.46

1.13

1.38

1.23

74

6.97

b-Eudesmol

–

0.32

0.78

0.96

0.86

75

6.98

Elemol

–

0.26

0.64

0.78

0.31

76

9.35

9b-Pimara-7,15-diene

–

0.32

0.79

0.97

0.86

77

9.36

Ent-sandaracopimaradiene

–

0.21

0.51

0.63

–

78

9.37

Stemar-13-ene

–

0.76

1.89

2.31

2.06

79

9.73

Ent-cassa-12,15-diene

–

–

0.69

0.85

0.76

80

17.05

d7-avenasterol

0.42

0.45

0.41

0.27

–

Total terpenoids

0.42

22.09

55.78

73.62

61.74

Alkaloid

81

1.49

Trigonelline

0.46

0.49

–

–

–

82

1.49

3-Ethyl-2,5-dimethylpyrazine

0.11

0.12

0.11

0.07

–

83

1.72

Pipecolic acid

0.12

0.13

–

–

–

84

1.72

2-Ethenyl-3,5-dimethylpyrazine

0.25

0.28

0.25

0.17

–

85

1.76

3-Isopropyl-2-methoxypyrazine

0.09

0.10

0.09

0.06

–

86

2.55

Xanthine

0.11

0.12

0.11

0.07

0.07

87

2.80

7-Methylxanthine

0.54

0.58

0.53

0.36

–

88

2.80

3-Methylxanthine

1.11

1.19

1.09

0.73

0.05

Total alkaloids

2.80

3.02

2.19

1.47

0.12

Furanoids

89

1.21

Furfural

0.65

–

–

–

–

90

1.26

2-Furfurylthiol

0.29

0.32

0.29

2.00

–

91

1.46

2,5-Dimethyl-4-hydroxy-3(2H)-furanone

0.33

0.35

0.32

–

–

92

1.71

3-Hydroxy-4,5-dimethylfuran-2(5H)-one

0.22

0.24

0.21

–

–

93

2.23

(-)-5-Ethyl-3-hydroxy-4-methyl-2(5H)-furanone

0.26

0.28

0.26

–

–

94

2.24

2-Ethyl-4-hydroxy-5-methylfuran-3-one

0.32

0.35

0.32

–

–

Total furanoids

2.08

1.53

1.39

0.20

0.00000

Saccharides

95

1.60

Arabinose

1.24

–

–

–

–

96

1.84

Rhamnose

1.61

–

–

–

–

97

2.54

Xylose

1.65

–

–

–

–

98

12.14

Inulobiose

2.17

–

–

–

–

99

12.96

3-Methylbutanoyl-1-O-b-D-glucopyranosyl-b-D-apiofuranoside

1.11

1.19

–

–

–

100

26.30

1-Kestose

1.64

–

–

–

–

101

26.31

Raffinose

1.24

–

–

–

–

102

26.31

Inulotriose

2.78

–

–

–

–

103

43.21

Inulotetraose

2.80

–

–

–

–

104

43.21

Nystose

2.49

–

–

–

–

105

46.17

Mannan

3.61

–

–

–

–

106

46.18

Stachyose

3.30

–

–

–

–

107

46.18

1(F)-a-D-galactosylraffinose

3.28

–

–

–

–

108

49.95

1F-fructofuranosylnystose

3.26

–

–

–

–

109

54.18

Glucomannan

2.42

–

–

–

–

Total saccharides

34.61

1.20

0.00000

0.00000

0.00000

Aromatic-Benzene

110

1.23

Benzaldehyde

0.27

0.29

0.26

0.18

–

111

1.29

Benzoic acid

0.46

0.49

–

–

0.56

112

1.30

2-Phenylethyl alcohol

–

0.62

1.54

1.88

–

113

1.71

2-Methoxy-4-vinylphenol

0.33

0.36

0.32

0.22

–

114

1.71

2,6-Dimethyl-decahydronaphthalene

–

0.11

0.29

0.35

–

115

1.76

4'-Ethylacetophenone

–

0.13

0.31

0.38

–

116

1.76

4'-Methoxy acetophenone

–

0.17

0.41

0.51

–

117

5.03

Isopentyl benzoate

0.46

0.49

0.45

0.30

–

Total aromatics

1.51

2.66

3.59

3.82

0.56

Miscellaneous

118

0.96

Methyl formate

–

0.56

1.39

1.71

–

119

0.96

1,3-pentadiene

–

0.26

0.64

0.78

0.70

120

1.17

2,3-Butanedione

0.35

0.37

0.34

0.23

–

121

1.20

2-Methylhexane

–

0.17

0.43

0.52

0.46

122

1.20

Methyl butyrate

–

0.41

1.01

1.23

–

123

1.21

Valeric acid

0.42

0.46

–

–

–

124

1.22

3-Hexanone

0.22

0.25

0.21

–

–

125

1.24

4-Heptenal

0.26

0.28

0.26

0.17

0.07

126

1.25

Succinic acid

0.18

0.19

–

–

–

127

1.29

Methyl 3-methylbutanoate

0.11

0.12

0.11

0.07

–

128

1.43

1,5-Octadien-3-one

0.39

0.43

0.39

0.26

0.21

129

1.46

Isopropyl butyrate

0.33

0.35

0.32

–

–

130

1.49

1-Octen-3-ol

–

0.41

1.00

1.23

1.10

131

1.52

1-Octen-3-one

0.26

0.28

0.26

0.17

0.06

132

1.54

a-ketoglutaric acid

0.33

0.35

–

–

0.40

133

1.56

3-Hexenyl acetate

–

1.07

2.64

3.23

–

134

1.72

(2R)-Nonan-2-ol

–

1.13

2.79

3.42

–

135

1.72

1-Butyl-2-propylcyclopentane

–

0.26

0.64

0.78

0.70

136

2.82

1-Octen-3-yl acetate

–

0.30

0.75

0.91

–

137

4.65

2,2,6-Trimethyldecane

–

0.45

1.12

1.37

–

138

4.65

4,6-Dimethylundecane

–

0.27

0.67

0.82

–

139

5.02

Quinic acid

0.61

0.65

–

–

–

140

7.34

2-Hexyl-1-decanol

–

0.52

1.30

1.59

1.41

Total miscellaneous

3.46

9.56

16.27

18.50

5.100

141

3.04

Gallic acid

2.39

2.58

–

–

2.96

142

5.18

Syringic acid

0.85

0.91

–

–

–

Total

100.00

100.02

100.00

100.00

100.00