Table 2 SCAPS simulation parameters for each layer.
Parameter | CZTS18 | ZnS30 | FTO31 |
---|---|---|---|
Thickness (µm) | 1.5 | 0.05 | 0.05 |
Band gap (eV) | 1.4 | 3.6 | 3.50 |
Electron affinity (eV) | 4.1 | 3.9 | 4.00 |
Relative dielectric constant | 9.0 | 9.0 | 9.0 |
Conduction band effective density of states per cm3 | 2.2 × 1018 | 2.2 × 1018 | 2.2 × 1018 |
Valence band effective density of states per cm3 | 1.8 × 1018 | 1.8 × 1019 | 1.8 × 1019 |
Mobility of e- (cm2 s−1 V−1) | 1.0 × 102 | 1.0 × 102 | 2.0 × 101 |
Mobility of hole (e+) (cm2 s−1 V−1) | 1.25 × 101 | 1.25 × 101 | 1.0 × 101 |
Thermal velocity of e− (cm s−1) | 1.0 × 107 | 1.0 × 107 | 1.0 × 107 |
Thermal velocity of hole (e+) (cm s−1) | 1.0 × 107 | 1.0 × 107 | 1.0 × 107 |
Shallow uniform donor density (nD) per cm3 | 0 | 1.1 × 1018 | 1.0 × 1019 |
Shallow uniform acceptor density (nA) per cm3 | 1.0 × 1019 | 0 | 0 |
Total defect density (Nt) per cm3 | 1.0 × 1015 | 1.0 × 1015 | 1.0 × 1015 |