Table 7 Comparison of the activity of Pd-BisPyP@bilayer-SiO2@NMP in the reaction of iodobenzene and phenylboronic acid with other catalysts.

From: Palladium anchored to BisPyP@bilayer-SiO2@NMP organic–inorganic hybrid as an efficient and recoverable novel nanocatalyst in suzuki and stille C–C coupling reactions

Catalyst

Conditions

Time (min)

Yield (%)

References

Mag-IL-Pd

K2CO3, H2O, 60 °C

360

95

67

Guanidine/Pd(OAc)2

K2CO3, H2O EtOH, rt

1200

99

68

NAS@Cu

CS2CO3, EtOH, 80 °C

120

97

39

Pd(II)-NHC complex

Cs2CO3, DMF, 100 °C

1440

99

69

NHC-Pd(II) complex

Cs2CO3, THF, 80 °C

720

88

70

Pd/Au NPs

K2CO3, EtOH/H2O, 80 °C

1440

88

71

CA/Pd(0)

K2CO3, H2O, 100 °C

120

94

72

Pd@SBA-15/ILDABCO

K2CO3, H2O, 80 °C

90

97

73

BisPyP@ySiO2@xSiO2@NMP

Na2CO3, PEG, 70 °C

5

99

[This work]

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