Table 5 Langmuir and Freundlich isotherm parameters and correlation coefficients for Pb+2, Cu+2, and Cd+2 adsorption onto CaCO3 and CaO.
Model | Parameters | CaCO3 | CaO | ||||
---|---|---|---|---|---|---|---|
Pb+2 | Cu+2 | Cd+2 | Pb+2 | Cu+2 | Cd+2 | ||
Langmuir | qmax (mg/g) | 270.3 | 73.53 | 0.61 | 1666.6 | 769.2 | 1250 |
KL (b) | 0.086 | 6.18 | 0.5 | 1.5 | 13 | 4 | |
RL | 0.019–0.011 | 0.003–0.001 | 0.038–0.013 | 0.0007–0.0003 | 0.0007–0.00011 | 0.001–0.0005 | |
R2 | 0.957 | 0.9845 | 0.9881 | 0.9997 | 0.862 | 0.999 | |
Freundlich | Kf | 324.56 | 98.22 | 1.53 | 3409.57 | 978.1 | 832.72 |
n | − 52.35 | 14.92 | − 5.49 | − 8.1 | − 4.73 | 3.8 | |
R2 | 0.3394 | 0.2277 | 0.7469 | 0.9357 | 0.94 | 0.9775 |