Table 3 The estimated constants of the models applied to the actual adsorption and desorption data of FDBD at different temperatures.
Parameter | Adsorption | Desorption | ||||
---|---|---|---|---|---|---|
25 °C | 35 °C | 45 °C | 25 °C | 35 °C | 45 °C | |
Peleg model | ||||||
C1 | 0.39 | 0.58 | 0.22 | 1.01 | 0.14 | 1.51 |
C2 | 2.94 | 2.75 | 1.50 | 4.41 | 0.00 | 5.26 |
C3 | 0.39 | 1.58 | 1.41 | 0.19 | 1.57 | 0.14 |
C4 | 2.94 | 13.67 | 6.38 | 0.03 | 5.01 | 0.22 |
GAB model | ||||||
Xm | 2.43 | 1.78 | 4.11 | 0.17 | 0.12 | 0.08 |
C | 0.05 | 0.04 | 0.02 | 13.8 | 25.2 | 74.62 |
K | 0.75 | 0.85 | 0.82 | 0.92 | 1.0 | 1.08 |
BET model | ||||||
Xm | 0.08 | 0.09 | 0.11 | 0.18 | 0.12 | 0.12 |
C | 1.66 | 0.88 | 1.18 | 25.3 | 26.15 | 3.48 |
Halsey model | ||||||
A | 0.08 | 0.09 | 0.11 | 0.09 | 0.14 | 0.14 |
B | 0.94 | 0.85 | 0.91 | 1.57 | 1.08 | 0.96 |
Oswin model | ||||||
A | 0.10 | 0.09 | 0.12 | 0.27 | 0.23 | 0.19 |
B | 0.88 | 1.01 | 0.95 | 0.46 | 0.72 | 0.83 |
Smith model | ||||||
A | -0.08 | − 0.11 | -0.12 | 0.10 | 0.03 | − 0.01 |
B | 0.29 | 0.34 | 0.40 | 0.26 | 0.33 | 0.33 |
Adam and shove model | ||||||
A | 0.01 | − 0.11 | − 0.14 | 0.15 | 0.08 | 0.03 |
B | − 0.25 | 1.23 | 1.64 | 0.36 | 0.80 | 0.77 |
C | 0.74 | − 3.62 | − 4.68 | − 1.39 | − 2.97 | − 2.63 |
D | 0.24 | 3.67 | 4.59 | − 1.01 | 3.58 | 3.19 |