Table 4 Values of thermodynamic adsorption parameters for the inhibitors on steel in 1 M HCl from the mass loss technique at different temperatures.

From: Novel gemini cationic thiazole-based surfactants as carbon steel corrosion inhibitors in 1 M HCl using experimental and theoretical tools

Surfactant name

Temp.,

\(\:\varvec{K}\)

\(\:{\varvec{K}}_{\varvec{a}\varvec{d}\varvec{s}}\)

L g− 1

\(\:\varDelta\:{\varvec{G}}_{\varvec{a}\varvec{d}\varvec{s}}^{^\circ\:}\)

kJ mol− 1

\(\:\varDelta\:{\varvec{H}}_{\varvec{a}\varvec{d}\varvec{s}}^{^\circ\:}\)

kJ mol− 1

R2

\(\:\varDelta\:{\varvec{S}}_{\varvec{a}\varvec{d}\varvec{s}}^{^\circ\:}\)

J mol− 1

TAC 6

303

609.8

-26.3

-48.5

0.93

-73.35

308

400.0

-25.6

-74.26

313

238.7

-24.7

-76.04

318

208.8

-24.6

-74.71

323

191.9

-24.3

-73.05

TAC 18

303

757.6

-26.8

-58.4

0.86

-104.61

308

289.9

-24.8

-108.97

313

194.6

-24.2

-109.51

318

174.8

-24.3

-107.51

323

164.7

-24.5

-105.21