Table 3 Kinetic fit parameters for the adsorption of acid blue 25 dye onto ZCPP41, ZCPP11, and ZCPP14 nanocomposites, derived from pseudo-first-order (PFO), pseudo-second-order (PSO), and intraparticle diffusion (IPD) models, with corresponding rate constants, capacities, and correlation coefficients (R²).
Catalyst | PFO model | PSO model | IPD model | ||||||
|---|---|---|---|---|---|---|---|---|---|
q1 (mg/g) | k1 (min− 1) | R2 | q2 (mg/g) | k2(g/mg min) | R2 | C | Kipd (mg/g min⁰·⁵) | R2 | |
ZCPP41 NCs | 118.31 | 0.273 | 0.933 | 174.3 ± 1.9 | 0.0071 | 0.998 | 145.13 | 4.33 | 0.965 |
ZCPP11 NCs | 94.63 | 0.19 | 0.908 | 151.5 ± 3.9 | 0.0033 | 0.993 | 89.70 | 5.93 | 0.963 |
ZCPP14 NCs | 33.18 | 0.17 | 0.802 | 53.5 ± 2.2 | 0.0025 | 0.980 | 24.22 | 3.37 | 0.966 |