Table 2 AAD% of pressure predictions by PR-EOS1 and Abudour et al. VTPR-EOS17.

From: A practical methodology for incorporating volume-translated equation of states in isochoric-isothermal phase equilibrium calculations for liquid phase pressure prediction

Substance

T, K

Range of ρ, mol/L

%ADD by PR-EOS1

%ADD By VTPR-EOS17

NDP

Carbon dioxide

250

23.0–30.0

96.79

9.57

80

280

20.0–30.0

310

18.0-28.5

340

15.0–28.0

Nitrogen

80

26.0–31.0

134.30

13.19

80

90

25.0–31.0

100

24.0-30.5

120

18.5–30.0

Methane

120

25.5–27.5

104.56

11.41

80

140

23.5–27.5

160

21.0–27.0

180

17.5–26.5

Ethane

180

18.0–19.0

160.35

18.03

100

200

17.5–19.0

250

15.0–19.0

300

12.0–19.0

Propane

220

13.5–14.5

122.69

15.13

100

240

13.0-14.5

300

11.0-14.3

360

9.0 -14.3

n-Butane

260

10.6–11.4

90.33

17.14

100

300

9.9–11.3

360

8.5–11.3

420

7.5–11.2

n-Pentane

300

8.6–9.5

56.53

14.63

80

350

7.9–9.3

400

7.0-9.1

450

6.1-9.0

n-Hexane

350

7.0–8.0

40.21

15.86

80

400

6.5–7.8

450

5.8–7.6

500

4.8–7.4

n-Nonane

430

4.7–5.6

42.14

20.12

100

480

4.5–5.6

530

4.0-5.6

580

3.6–5.6

n-Decane

440

4.3-5.0

71.57

18.16

80

500

3.9-5.0

560

3.6-5.0

610

3.4-5.0

n-Dodecane

460

3.6–4.1

145.19

15.77

80

520

3.3–4.1

580

3.1–4.1

650

2.8–4.1

Ethylene

160

20.6–21.5

135.39

28.17

100

200

18.6–20.5

240

15.6–19.2

280

12.0-17.8

Cyclohexane

350

8.5–9.3

87.14

19.99

80

400

8.0–9.0

500

6.2–8.5

550

4.5–8.3

Benzene

400

9.7–11.2

66.32

23.93

100

450

8.9–11.2

500

8.4–11.2

550

7.1–11.2

Toluene

380

8.5–9.1

36.02

14.09

80

450

7.7–9.1

520

7.0-9.1

580

6.0-9.1

Tetrafluoromethane

160

17.4–19.2

84.98

14.59

80

180

16.0-18.5

200

13.9–17.8

220

12.6–17.0

Acetone

350

12.5–13.9

230.44

19.98

100

400

11.5–13.5

450

10.0–13.0

500

9.0-12.6

Ethanol

380

15.3–16.2

270.69

42.659

80

420

14.1–15.5

460

12.4–14.6

500

10.2–14.6

Overall

  

109.75

18.47

1580