Table 2 AAD% of pressure predictions by PR-EOS1 and Abudour et al. VTPR-EOS17.
Substance | T, K | Range of ρ, mol/L | %ADD by PR-EOS1 | %ADD By VTPR-EOS17 | NDP |
---|---|---|---|---|---|
Carbon dioxide | 250 | 23.0–30.0 | 96.79 | 9.57 | 80 |
280 | 20.0–30.0 | ||||
310 | 18.0-28.5 | ||||
340 | 15.0–28.0 | ||||
Nitrogen | 80 | 26.0–31.0 | 134.30 | 13.19 | 80 |
90 | 25.0–31.0 | ||||
100 | 24.0-30.5 | ||||
120 | 18.5–30.0 | ||||
Methane | 120 | 25.5–27.5 | 104.56 | 11.41 | 80 |
140 | 23.5–27.5 | ||||
160 | 21.0–27.0 | ||||
180 | 17.5–26.5 | ||||
Ethane | 180 | 18.0–19.0 | 160.35 | 18.03 | 100 |
200 | 17.5–19.0 | ||||
250 | 15.0–19.0 | ||||
300 | 12.0–19.0 | ||||
Propane | 220 | 13.5–14.5 | 122.69 | 15.13 | 100 |
240 | 13.0-14.5 | ||||
300 | 11.0-14.3 | ||||
360 | 9.0 -14.3 | ||||
n-Butane | 260 | 10.6–11.4 | 90.33 | 17.14 | 100 |
300 | 9.9–11.3 | ||||
360 | 8.5–11.3 | ||||
420 | 7.5–11.2 | ||||
n-Pentane | 300 | 8.6–9.5 | 56.53 | 14.63 | 80 |
350 | 7.9–9.3 | ||||
400 | 7.0-9.1 | ||||
450 | 6.1-9.0 | ||||
n-Hexane | 350 | 7.0–8.0 | 40.21 | 15.86 | 80 |
400 | 6.5–7.8 | ||||
450 | 5.8–7.6 | ||||
500 | 4.8–7.4 | ||||
n-Nonane | 430 | 4.7–5.6 | 42.14 | 20.12 | 100 |
480 | 4.5–5.6 | ||||
530 | 4.0-5.6 | ||||
580 | 3.6–5.6 | ||||
n-Decane | 440 | 4.3-5.0 | 71.57 | 18.16 | 80 |
500 | 3.9-5.0 | ||||
560 | 3.6-5.0 | ||||
610 | 3.4-5.0 | ||||
n-Dodecane | 460 | 3.6–4.1 | 145.19 | 15.77 | 80 |
520 | 3.3–4.1 | ||||
580 | 3.1–4.1 | ||||
650 | 2.8–4.1 | ||||
Ethylene | 160 | 20.6–21.5 | 135.39 | 28.17 | 100 |
200 | 18.6–20.5 | ||||
240 | 15.6–19.2 | ||||
280 | 12.0-17.8 | ||||
Cyclohexane | 350 | 8.5–9.3 | 87.14 | 19.99 | 80 |
400 | 8.0–9.0 | ||||
500 | 6.2–8.5 | ||||
550 | 4.5–8.3 | ||||
Benzene | 400 | 9.7–11.2 | 66.32 | 23.93 | 100 |
450 | 8.9–11.2 | ||||
500 | 8.4–11.2 | ||||
550 | 7.1–11.2 | ||||
Toluene | 380 | 8.5–9.1 | 36.02 | 14.09 | 80 |
450 | 7.7–9.1 | ||||
520 | 7.0-9.1 | ||||
580 | 6.0-9.1 | ||||
Tetrafluoromethane | 160 | 17.4–19.2 | 84.98 | 14.59 | 80 |
180 | 16.0-18.5 | ||||
200 | 13.9–17.8 | ||||
220 | 12.6–17.0 | ||||
Acetone | 350 | 12.5–13.9 | 230.44 | 19.98 | 100 |
400 | 11.5–13.5 | ||||
450 | 10.0–13.0 | ||||
500 | 9.0-12.6 | ||||
Ethanol | 380 | 15.3–16.2 | 270.69 | 42.659 | 80 |
420 | 14.1–15.5 | ||||
460 | 12.4–14.6 | ||||
500 | 10.2–14.6 | ||||
Overall | 109.75 | 18.47 | 1580 |