Table 1 Electrical parameters used for CsPb0.75Sn0.25IBr2/Cs2TiI6 tandem solar cell, input to SCAPS − 1D simulator50,51,52,53,54,55,56,57,58,59,60.

From: Current matched all perovskite tandem solar cells with low lead perovskites achieving 31.9% efficiency and enhanced stability

Electrical parameters

TiO2

N- PDI

CsPb0.75Sn0.25IBr2

Cs2TiI6

Spiro-OMeTAD

PEDOT

Thickness (nm)

50

50

100 − 1000

100–1000

100

100

Band gap (eV)

3.2

2.33

1.78

1.02

3

1.6

Electron affinity (eV)

4.26

3.72

3.7

4

2.45

3.4

Dielectric Permittivity

9

9

8

6.9

3

3

CB effective density of states (1/cm3)

2.2 × 1018

2.2 × 1018

2 × 1018

4.96 × 1019

1 × 1019

2.2 × 1018

VB effective density of states (1/cm3)

1.8 × 1019

1.8 × 1019

5 × 1018

1.75 × 1019

1 × 1019

1.8 × 1019

Electron/hole thermal velocity (cm/s)

1 × 107

1 × 107

1 × 107

1 × 107

1 × 107

1 × 107

Electron/hole mobility (cm2/Vs)

20/10

0.013/0.013

20/20

0.236 /0.171

0.0002/ 0.0002

0.045/0.045

Donor density (1/cm3)

9 × 1016

9 × 1016

-

3 × 1019

-

-

Acceptor density (1/cm3)

-

-

-

3 × 1018

2 × 1018

1 × 1019

Total defect density (1/cm3)

1015

1015

1015

1014

1014

1015