Table 3 Standard partial molar volumes (\(~V_{\varphi }^{0}~\)), adjustable parameter of Eq. 2 (\(~{S_v}~\)) and standard deviations (\(\sigma (~v_{\varphi }^{0}~)\)) for GBP in aqueous solutions of betaine-based compounds at 298 K.a
am (mol kg−1) | 106 \(~V_{\varphi }^{0}~\) (m3 mol−1) | 106Sv (m3 mol−2kg) | (\(\sigma (~V_{\varphi }^{0}~)\)) |
|---|---|---|---|
Betaine | |||
0.0098 | 138.677 ± 0.050 | 64.835 ± 0.300 | 0.04 |
0.0297 | 142.010 ± 0.015 | 31.385 ±0. 631 | 0.02 |
0.0501 | 142.916 ± 0.040 | 8.232 ± 0.800 | 0.09 |
DES (betaine-urea 1:2) | |||
0.0103 | 141.695 ± 0.054 | 67.432 ±0. 333 | 0.07 |
0.0299 | 142.292 ± 0.0751 | 31.835 ± 0.160 | 0.10 |
0.0501 | 142.407 ± 0.030 | 39.798 ± 0.894 | 0.04 |
IL (betaine octyl ester chloride) | |||
0.0103 | 140.664 ± 0.070 | 43.886 ± 0.796 | 0.01 |
0.0294 | 141.481 ± 0.093 | 76.856 ± 0.213 | 0.03 |
0.0496 | 141.791 ± 0.137 | 93.956 ± 0.931 | 0.08 |