Abstract
Rapid urbanization and land use and land cover (LULC) change have affected groundwater dynamics and its quality in many river basins. The present study uses an integrated framework combining multi-temporal Landsat imagery, geospatial analysis, multivariate statistics, and Machine Learning (ML) approaches to understand LULC changes and groundwater dynamics and its quality degradation. The supervised classification was used in the present study, which shows that built-up land increased significantly from 12.3% (329.13 km2) in 2003 to 44.4% (1,187.11 km2) in 2023, mainly due to the conversion of agricultural and forested land. Furthermore, future LULC dynamics by the CA-Markov model indicate continuous landscape transformation, with net conversions into built-up and forested areas during the periods 2023–2033 and 2033–2043, respectively, while there is a decline in water bodies and agricultural land use, and their rates of change stabilize over the periods approaching 2043–2050. Multivariate statistical analyses, such as correlation analysis, Principal Component Analysis (PCA), and Cluster Analysis, identify both geogenic processes and human activities as dominant determinants of groundwater hydrochemistry. To investigate the relationships between physicochemical parameters and nitrate variability, 3 ML models were employed: Random Forest (RF), Support Vector Regression (SVR), and XGBoost. Model interpretation using SHapley Additive exPlanations (SHAP) showed that Mg2+, Ca2+, and alkalinity are the significant factors influencing nitrate distribution, reflecting buffering reactions and redox-controlled processes. An integrated framework combining LULC, hydrogeochemical, and ML techniques provides a strong foundation for assessing groundwater. It offers insights into sustainable land-use planning and groundwater management in rapidly urbanizing tropical basins.
Data availability
All data generated or analysed during this study are included in this published article [and its supplementary information files].
References
Dong, S., Guo, H., Chen, Z., Pan, Y. & Gao, B. Spatial Stratification Method for the Sampling Design of LULC Classification Accuracy Assessment: A Case Study in Beijing, China. Remote Sens. (Basel) https://doi.org/10.3390/rs14040865 (2022).
Li, X. et al. Hydrochemical characteristics and nitrate health risk assessment in a shallow aquifer: insights from a typical Low-Mountainous region. Water 17 (24), 3516. https://doi.org/10.3390/w17243516 (2025).
Siddiqui, K. Impact of population changes and economic growth in China and India. World (2024).
UN-DESA, World Population Prospects https://www.un.org/development/desa/pd/2022
Murmu, J., Radhadevi, L., Pande, C., Bandaru, M. & Kumar, M. Indicators of sustained agriculture, impacts of LULC and weather parameters on ET: Case study in Chota Nagpur Plateau. Environ. Sustain. Indic. 27, 100836. https://doi.org/10.1016/j.indic.2025.100836 (2025).
Tassi, A. & Vizzari, M. Object-oriented lulc classification in Google Earth engine combining snic, glcm, and machine learning algorithms. Remote Sens. (Basel). 12 (22), 3776 (2020).
Shaji, J., Sajith, S. L., Joseph, J. & Ramachandran, K. K. LULC change along Central Kerala coast and perception on implementation of CRZ notification. National Conf. Geosp. Technol. (2017).
Pandey, S. & Kumari, N. Prediction and monitoring of LULC shift using cellular automata-artificial neural network in Jumar watershed of Ranchi District, Jharkhand. Environ. Monit. Assess. https://doi.org/10.1007/s10661-022-10623-6 (2023).
Nair, S. B. & CJ, P. Urbanization in Kerala—What Does the Census Data Reveal? J. Human Dev. vol. (2017).
Gopinath, G. Chemistry of groundwater in lateritic terrains of the Muvattupuzha river. (2017).
Giriraj, A., Irfan-Ullah, M., Murthy, M. S. R. & Beierkuhnlein, C. Modelling spatial and temporal forest cover change patterns (1973–2020): A case study from South Western Ghats (India). Sensors 8(10), 6132–6153. https://doi.org/10.3390/s8106132 (2008).
Reddy, C. S. Assessment and monitoring of long-term forest cover changes (1920–2013) in Western Ghats biodiversity hotspot. http://www.natureasia.com
Zegaar, A., Ounoki, S. & Telli, A. Machine learning for groundwater quality classification: A step towards economic and sustainable groundwater quality assessment process. Water Resour. Manage. 38 (2), 621–637 (2024).
Che Nordin, N. F. et al. Groundwater quality forecasting modelling using artificial intelligence: A review. Groundw. Sustain. Dev. https://doi.org/10.1016/j.gsd.2021.100643 (2021).
Yang, S. et al. Spatial mapping and prediction of groundwater quality using ensemble learning models and SHapley additive explanations with Spatial uncertainty analysis. Water (Switzerland). 16 (17), Sep–2024. https://doi.org/10.3390/w16172375 (2024).
Xiong, H. et al. Critical role of vegetation and human activity indicators in the prediction of shallow groundwater quality distribution in Jianghan plain with LightGBM algorithm and SHAP analysis. Chemosphere 376, 144278. https://doi.org/10.1016/j.chemosphere.2025.144278 (2025).
Pandya, H., Jaiswal, K. & Shah, M. A comprehensive review of machine learning algorithms and its application in groundwater quality prediction. Arch. Comput. Methods Eng. 31 (8), 4633–4654 (2024).
Maya, K., Santhosh, V., Padmalal, D. & Kumar, S. R. A. Impact of mining and quarrying in Muvattupuzha river basin, Kerala-An overview on its environmental effects. Bonfring Int. J. Industrial Eng. Manage. Sci. 2 (1), 36–40 (2012).
Anand, B., Rekha, R. S., Radhakrishnan, N. & Ramaswamy, K. Analysis of LULC change dynamics and its impact assessment using CA-ANN model in part of Coimbatore region, India. GeoJournal https://doi.org/10.1007/s10708-023-10944-0 (2023).
Kumar, A. A., Dipu, S. & Sobha, V. Seasonal variation of heavy metals in Cochin estuary and adjoining periyar and Muvattupuzha rivers, Kerala, India. Global J. Environ. Res. 5 (1), 15–20 (2011).
Ali, H. Y., Priju, C. P. & Prasad, N. B. N. Delineation of Groundwater Potential Zones in Deep Midland Aquifers Along Bharathapuzha River Basin. Kerala Using Geophysical Methods, Aquat Procedia. 4, 1039–1046. https://doi.org/10.1016/j.aqpro.2015.02.1 (2015).
Shahul Hameed, A. et al. Isotopic characterization and mass balance reveals groundwater recharge pattern in Chaliyar river basin Kerala, India.. J Hydrol Reg Stud. 4, 48–58. https://doi.org/10.1016/j.ejrh.2015.01.003 (2015).
Ribinu, S. K., Prakash, P., Khan, A. F., Bhaskar, N. P. & Arunkumar, K. S. Hydrogeochemical characteristics of groundwater in Thoothapuzha River Basin, Kerala, South India. Total Environ. Res. Themes https://doi.org/10.1016/j.totert.2022.100021 (2022).
Alappuzha, K. Government of Kerala groundwater department, vol. no. May, 1–19. (2020).
Parthasarathy, K. S. S. & Kundapura, S. Spatio-Temporal Analysis on the Optical Properties of Vembanad Lake, Kerala, India–A Remote Sensing Approach, (2023).
Devi, A. B., Deka, D., Aneesh, T. D., Srinivas, R. & Nair, A. M. Predictive modelling of land use land cover dynamics for a tropical coastal urban City in Kerala, India. Arab. J. Geosci. 15 (5), 399 (2022).
Prasad, G. & Ramesh, M. V. Spatio-Temporal Analysis of Land Use/Land Cover Changes in an Ecologically Fragile Area—Alappuzha District, Southern Kerala, India. Nat. Resour. Res. 28, 31–42. https://doi.org/10.1007/s11053-018-9419-y (2019).
Selvan, S. C., Kankara, R. S., Prabhu, K. & Rajan, B. Shoreline change along Kerala, south-west Coast of India, using geo-spatial techniques and field measurement. Nat. Hazards. 100 (1), 17–38 (2020).
Balchand, A. N. & Nambisan, P. N. K. Effect of Puip-Paper effluents on the water quality of Muvattupuzha river emptying into Cochin backwaters, (1986).
Beegam, S. N. & ArulRaj, P. G. Journal of critical reviews effect of population growth on land use and runoff of Muvattupuzha Sub-basin.
Reconaissance Survey Report Sand Auditing Of Muvattupuzha River. Ernakulam District, 2019. [Online]. Available: www.ties.org.in
Hasan, M., Haque, R. & Rahman, M. Case Studies in Chemical and Environmental Engineering Identifying the land use land cover (LULC) changes using remote sensing and GIS approach: A case study at Bhaluka in Mymensingh, Bangladesh. 7, (2022).
Njoku, E. A. & Tenenbaum, D. E. Remote Sensing Applications: Society and Environment Quantitative assessment of the relationship between land use / land cover (LULC), topographic elevation and land surface temperature (LST) in Ilorin, Nigeria. 27, (2022).
Townshend, J. R., Gayler, J. R., Hardy, J. R., Jackson, M. J. & Baker, J. R. Remote sensing letters: preliminary analysis of LANDSAT-4 thematic mapper products. Int. J. Remote Sens. 4 (4), 817–828. https://doi.org/10.1080/01431168308948606 (1983).
Handavu, F., Chirwa, P. W. C. & Syampungani, S. Socio-economic factors influencing land-use and land-cover changes in the Miombo woodlands of the copperbelt Province in Zambia. Policy Econ. 100, 75–94. https://doi.org/10.1016/j.forpol.2018.10.010 (2019).
Krishnaraj, A. & Honnasiddaiah, R. Multi-spatial-scale land/use land cover influences on seasonally dominant water quality along middle Ganga basin. Environ. Monit. Assess. 195 (12), 1434. https://doi.org/10.1007/s10661-023-12059-y (2023).
Fan, F., Weng, Q. & Wang, Y. Land use and land cover change in Guangzhou, China, from 1998 to 2003, based on landsat TM /ETM+ imagery. 1323–1342, (2007).
Thein, A. M. & Htwe, A. N. Based on Principal Component Analysis of Land Use Land Cover Change Detection Using Landsat Satellite Images (Case study Mandalay City). IEEE Conf. Comput. Appl. (ICCA) https://doi.org/10.1109/ICCA51723.2023.10181968 (2023).
Khan, R. & Jhariya, D. C. Assessment of land-use and land-cover change and its impact on groundwater quality using remote sensing and GIS techniques in Raipur City, Chhattisgarh, India. J. Geol. Soc. India. 92, 59–66 (2018).
Zhang, Z. et al. Impact of Land Use/Land Cover and Landscape Pattern on Water Quality in Dianchi Lake Basin, Southwest of China. Sustain. https://doi.org/10.3390/su15043145 (2023).
Islam, M. Y., Nasher, N. M. R., Karim, K. H. R. & Rashid, K. J. Quantifying forest land-use changes using remote-sensing and CA-ANN model of Madhupur Sal Forests, Bangladesh. Heliyon 9 (5), e15617. https://doi.org/10.1016/j.heliyon.2023.e15617 (2023).
Dash, P., Sanders, S. L., Parajuli, P. & Ouyang, Y. Improving the accuracy of land use and land cover classification of landsat data in an agricultural watershed. Remote Sens. (Basel). 15 (16). https://doi.org/10.3390/rs15164020 (Aug. 2023).
Potapov, P. The Global 2000–2020 Land Cover and Land Use Change Dataset Derived From the Landsat Archive: First Results. Front. Remote Sens. https://doi.org/10.3389/frsen.2022.856903 (2022).
Brontowiyono, W., Asmara, A. A., Jana, R., Yulianto, A. & Rahmawati, S. Land-Use Impact on Water Quality of the Opak Sub-Watershed, Yogyakarta, Indonesia. Sustain. https://doi.org/10.3390/su14074346 (2022).
Oliphant, A. J. et al. Mapping cropland extent of Southeast and Northeast Asia using multi-year time-series Landsat 30-m data using a random forest classifier on the Google Earth Engine Cloud. Int. J. Appl. Earth Observation Geoinform. 81, 110–124 (2019).
Patel, S., Indraganti, M. & Jawarneh, R. N. A comprehensive systematic review: impact of land Use/ land cover (LULC) on land surface temperatures (LST) and outdoor thermal comfort. Build. Environ. 249, 111130. https://doi.org/10.1016/j.buildenv.2023.111130 (2024).
BIS. Indian Standard Drinking Water Specification (Second Revision), Bureau of Indian Standards, vol. IS 10500, no. May, pp. 1–11, [Online]. (2012). Available: http://cgwb.gov.in/Documents/WQ-standards.pdf
Guidelines for Drinking-water Quality FIRST ADDENDUM TO THIRD EDITION. Volume 1 Recommendations WHO Library Cataloguing-in-Publication Data, (2006).
Srivastava, M., Srivastava, P. K., Kumar, D. & Kumar, A. A comprehensive assessment of uranium in groundwater using IDW and EWQI in the Sahibganj district of Jharkhand, India. (2024).
Dewana, B. R., Prasetyo, S. Y. J. & Hartomo, K. D. Comparison of IDW and Kriging Interpolation Methods Using Geoelectric Data to Determine the Depth of the Aquifer in Semarang, Indonesia. Jurnal Ilmiah Teknik Elektro Komputer dan. Informatika 8(2), 215. https://doi.org/10.26555/jiteki.v8i2.23260 (2022).
Mondal, K. C., Rathod, K. G., Joshi, H. M. & Mandal, H. S. Impact of land-use and land-cover change on groundwater quality and quantity in the Raipur, Chhattisgarh, India: A remote sensing and GIS approach. IOP Conf. Ser. Earth Environ. Sci. https://doi.org/10.1088/1755-1315/597/1/012011 (2021).
Benaissa, C., Bouhmadi, B. & Rossi, A. An assessment of the physicochemical, bacteriological quality of groundwater and the water quality index (WQI) used GIS in Ghis Nekor, Northern Morocco. Sci. Afr. https://doi.org/10.1016/j.sciaf.2023.e01623 (2023).
Pareta, K. et al. Groundwater quality assessment for drinking and irrigation purposes in the Ayad river basin, Udaipur (India). Groundw. Sustain. Dev. 27, 101351. https://doi.org/10.1016/j.gsd.2024.101351 (2024).
yedem Fentie, A., Mengistu, D. & Molla, G. Assessment of groundwater quality for drinking purpose using GIS based WQI methods, in Koga irrigation. Water Sci. 38 (1), 618–631 (2024).
Deshmukh, K. K. & Aher, S. P. Assessment of the impact of municipal solid waste on groundwater quality near the Sangamner City using GIS approach. Water Resour. Manage. 30, 2425–2443 (2016).
Dhaduti, M. S., Hunashyal, A. M., Dhaduti, S. C., Jalagar, S. R. & Mathad, S. N. Assessment of groundwater quality of hubballi City, Karnataka, India by using Canadian Council of ministers of the environment water quality index, weighted arithmetic water quality index and Geospatial techniques. J. Institution Eng. (India): Ser. A. 105 (3), 581–587 (2024).
Kushe, V. P., Mishra, S. S. & Charhate, S. Assessment of ground water quality parameters during post monsoon season in three taluka of Sindhudurg district of Maharashtra using water quality index. Sādhanā 49 (2), 171 (2024).
Harman, B. I., Koseoglu, H. & Yigit, C. O. Performance evaluation of IDW, Kriging and multiquadric interpolation methods in producing noise mapping: A case study at the city of Isparta, Turkey. Appl. Acoust. 112, 147–157. https://doi.org/10.1016/j.apacoust.2016.05.024 (2016).
Kawo, N. S. & Karuppannan, S. Groundwater quality assessment using water quality index and GIS technique in Modjo river Basin, central Ethiopia. J. Afr. Earth Sc. 147, 300–311 (2018).
Bashir, E., Wasay, M. A., Naseem, S., Kaleem, M. & Shahab, B. Evaluation of groundwater quality from Shah Faisal Town, Karachi employing SPSS and GIS-IDW techniques. J. Himal. Earth Sci. 57 (2), 32–53 (2024).
Workneh, H. T., Chen, X., Ma, Y., Bayable, E. & Dash, A. Comparison of IDW, Kriging and orographic based linear interpolations of rainfall in six rainfall regimes of Ethiopia. J. Hydrol. Reg. Stud. https://doi.org/10.1016/j.ejrh.2024.101696 (2024).
Singh, R., Singh, A., Majumder, C. B. & Vidyarthi, A. K. Impact of pH, TDS, Chloride, and nitrate on the groundwater quality using Entropy-Weighted water quality index and statistical analysis: A case study in the districts of North India. Water Conserv. Sci. Eng. 9 (2), 86 (2024).
Kefi, M., Aden, M. M. & Ben Ali, B. Water quality monitoring for irrigation by the integration of water quality index in a geographic information system environment in Chiba watershed, Nabeul, Tunisia. Water Conserv. Sci. Eng. 9 (1), 20 (2024).
Geris, J. et al. Predicting land use and land cover changes for sustainable land management using CA-Markov modelling and GIS techniques surface water-groundwater interactions and local land use control water quality impacts of extreme rainfall and flooding in a vulnerable semi-arid region of Sub-Saharan Africa. J. Hydrol. (Amst) 609, 127834. https://doi.org/10.1016/j.jhydrol.2022.127834 (2022).
Jothi, S. V. M. P. Detecting outliers in data streams using clustering algorithms. Int. J. Innovative Res. Comput. Communication Eng. 1, 8 (2013).
Duraj, A. & Szczepaniak, P. S. Outlier detection in data streams—A comparative study of selected methods. Procedia Comput. Sci. 192, 2769–2778 (2021).
Angiulli, F. & Fassetti, F. Distance-based outlier queries in data streams: the novel task and algorithms. Data Min. Knowl. Discov. 20 (2), 290–324 (2010).
Development of. A PCA-based land use/land cover classification utilizing Sentinel-2 time series. Middle East. J. Agric. Res. https://doi.org/10.36632/mejar/2022.11.2.42 (2022).
Pandey, H. K., Singh, V. K., Srivastava, S. K. & Singh, R. P. Groundwater quality assessment using PCA and water quality index (WQI) in a drought-prone area. Sustain. Water Resour. Manag. 9 (6), 197 (2023).
Torres-Martínez, J. A., Mahlknecht, J., Kumar, M., Loge, F. J. & Kaown, D. Advancing groundwater quality predictions: machine learning challenges and solutions. Sci. Total Environ. 949, 174973. https://doi.org/10.1016/j.scitotenv.2024.174973 (2024).
El-Rawy, M. et al. An Integrated GIS and Machine-Learning Technique for Groundwater Quality Assessment and Prediction in Southern Saudi Arabia. Water https://doi.org/10.3390/w15132448 (2023).
Sahour, S. et al. Evaluation of machine learning algorithms for groundwater quality modeling. Environ. Sci. Pollut. Res. 30 (16), 46004–46021 (2023).
Siqi, W., Qiang, L., Xifeng, G., En, Z. & Jianping, Y. Fast and unsupervised outlier removal by recurrent adaptive reconstruction extreme learning machine. Int. J. Mach. Learn. Cybernet. 10 (12), 3539–3556 (2019).
Haggerty, R., Sun, J., Yu, H. & Li, Y. Application of machine learning in groundwater quality modeling-A comprehensive review. Water Res. 233, 119745 (2023).
Yu, T. K. et al. Predicting potential soil and groundwater contamination risks from gas stations using three machine learning models (XGBoost, LightGBM, and),Process Saf. Environ. Prot., 199, 107249, doi: https://doi.org/10.1016/j.psep.2025.107249. (2025).
Weith, T. et al. Human-Environment Interactions 8 Sustainable Land Management in a European Context.http://www.springer.com/series/8599
Connor, R. The United Nations world water development report 2015: water for a sustainable world. in World Water assessment Programme. U.N. Educ. Sci. Cultural Organization. https://books.google.co.in/books?id=zQV1CQAAQBAJ 2015. https://books.google.co.in/books?id=zQV1CQAAQBAJ
Hua, Y., Yan, D. & Liu, X. Environmental and Sustainability Indicators Assessing synergies and trade-offs between ecosystem services in highly urbanized area under different scenarios of future land use change. Environmental and Sustainability Indicators. 22, 100350. https://doi.org/10.1016/j.indic.2024.100350 (2024).
Tahir, Z. et al. Predicting land use and land cover changes for sustainable land management using CA-Markov modelling and GIS techniques. Sci. Rep. https://doi.org/10.1038/s41598-025-87796-w (2025).
Ariti, A. T., van Vliet, J. & Verburg, P. H. Land-use and land-cover changes in the central rift Valley of ethiopia: assessment of perception and adaptation of stakeholders. Appl. Geogr. 65, 28–37. https://doi.org/10.1016/j.apgeog.2015.10.002 (2015).
Kumar, V. & Agrawal, S. Urban modelling and forecasting of landuse using SLEUTH model. Int. J. Environ. Sci. Technol. https://doi.org/10.1007/s13762-022-04331-4 (2023).
Nery, T. et al. Comparing supervised algorithms in Land Use and Land Cover classification of a Landsat time-series. IEEE Int. Geosci. Remote Sens. Symp. (IGARSS), IEEE 5165–5168. (2016).
Priyadarisini, D. & Umadevi, G. A System Dynamics Model for Assessing Land-Use Transport Interaction Scenarios in Chennai, India. Sustain. https://doi.org/10.3390/su15076297 (2023).
Miao, Z., Brusseau, M. L., Carroll, K. C., Carreón-Diazconti, C. & Johnson, B. Sulfate reduction in groundwater: characterization and applications for remediation. Environ. Geochem. Health. 34 (4), 539–550. https://doi.org/10.1007/s10653-011-9423-1 (2012).
Das, B. & Pal, S. C. Assessment of groundwater recharge and its potential zone identification in groundwater-stressed Goghat-I block of Hugli District, West Bengal, India. Environ. Dev. Sustain. 22 (6), 5905–5923. https://doi.org/10.1007/s10668-019-00457-7 (2020).
Lei, X. et al. Coupling coordination analysis of urbanization and ecological environment in Chengdu-Chongqing urban agglomeration. Ecol. Ind. 161 (December 2023), 111969. https://doi.org/10.1016/j.ecolind.2024.111969 (2024).
Bao, C. & He, D. Scenario modeling of urbanization development and water scarcity based on system dynamics: A case study of Beijing–Tianjin–Hebei urban agglomeration, China. Int. J. Environ. Res. Public. Health https://doi.org/10.3390/ijerph16203834 (2019).
Ozhukayil, J., Sebastian, L. & Chandramohanakumar, N. Comparative study on dissolved trace metal concentrations of iron and manganese in Muvattupuzha river. Int. J. Math. Trends Technol-IJMTT, 38, (2016).
Shaina Beegam, N., ArulRaj, G. P. & Brema, J. An examination of land use and land cover changes in muvattupuzha river basin using GIS. Int. J. Recent Technol. Eng. 8, 7957–7960 (2019).
44_Kerala MPR June 2020.
muvattupuzha area ssurrounding industries.
Wang, H., He, Q., Liu, X., Zhuang, Y. & Hong, S. Landscape and urban planning global urbanization research from 1991 to 2009: A systematic research review. Landsc. Urban Plan. 104, 3–4. https://doi.org/10.1016/j.landurbplan.2011.11.006 (2012).
Keerthi Naidu, B. N. & Chundeli, F. A. Assessing LULC changes and LST through NDVI and NDBI Spatial indicators: a case of Bengaluru, India. GeoJournal 88 (4), 4335–4350. https://doi.org/10.1007/s10708-023-10862-1 (2023).
Abbas, Z., Yang, G., Zhong, Y. & Zhao, Y. Spatiotemporal change analysis and future scenario of lulc using the CA-ANN approach: A case study of the greater bay area, China. Land. (Basel) https://doi.org/10.3390/land10060584 (2021).
Patel, A. et al. Results in Engineering Novel approach for the LULC change detection using GIS & Google Earth Engine through spatiotemporal analysis to evaluate the urbanization growth of Ahmedabad city. 21 (2023).
Vijay, A. & Varija, K. Spatio-temporal classification of land use and land cover and its changes in Kerala using remote sensing and machine learning approach. Environ. Monit. Assess. 196 (5), 459 (2024).
Akhila, R. & Pramada, S. K. Land use land cover change detection and prediction using land change modeler–A case study of kerala: R Akhila and SK Pramada. J. Earth Syst. Sci. 134 (3), 138 (2025).
Prakasam, C. & R, A. Impact of changing urban landscapes on forest degradation: A study on a part of Western Ghats, India. Environ. Monit. Assess. 196 (3), 256 (2024).
Chinnasamy, P. & Honap, V. U. Spatiotemporal variations in soil loss across the biodiversity hotspots of Western Ghats Region, India. J. Earth Syst. Sci. 132 (2), 90 (2023).
Drissia, T. K., Sreya, P., Eldho, T. I. & Dinesan, V. P. Impact of land use/land cover and climate change on streamflow variations in heterogeneous river basins of south-western India. Int. J. River Basin Manag. 1–18, (2024).
Nawab, N. P. S., Nimitha, M., Muthukumar, A. & Muthuchamy, M. Remote sensing and GIS for monitoring and assessing forest susceptibility to climate change: A spatio-temporal study on protected area of Western ghats, India. J. Sci. Res. 66 (4), 7–14 (2022).
Arumugam, T., Kinattinkara, S., Velusamy, S., Shanmugamoorthy, M. & Murugan, S. GIS based landslide susceptibility mapping and assessment using weighted overlay method in wayanad: A part of Western Ghats, Kerala. Urban Clim. 49, 101508 (2023).
Natarajan, S. Flood Inundation Mapping by Multi-criteria Decision Analysis—A Study on Recent Floods—Idukki District, Kerala-India. Int. Conf. Adv. Mater. Modeling Analysis Sustain. Resilient Infrastruct. 191–201. (2025).
Khan, H. H., Khan, A., Ahmed, S. & Perrin, J. GIS-based impact assessment of land-use changes on groundwater quality: study from a rapidly urbanizing region of South India. Environ. Earth Sci. 63, 1289–1302 (2011).
Acharya, S., Hori, T. & Karki, S. Assessing the spatio-temporal impact of landuse landcover change on water yield dynamics of rapidly urbanizing Kathmandu Valley watershed of Nepal. J. Hydrol. Reg. Stud. 50, 101562. https://doi.org/10.1016/j.ejrh.2023.101562 (2023).
de Gomes, K. M., Saad, S. I. & Mota da Silva, J. Hydrological implications of agricultural expansion on natural and degraded lands in Northeastern Brazil. J. South. Am. Earth Sci. 167, 105785. https://doi.org/10.1016/j.jsames.2025.105785 (2025).
Nambiar, S. R., Satheendran, S. S. & Dhanya, R. Land Use/Land Cover Changes of Kannur District, Kerala From 1969 to 2024: A Geospatial Investigation. Int. Conf. Adv. Mater. Modeling Analysis Sustain. Resilient Infrastruct. 133–143. (2025).
Varunprasath, K., Islam, M. N. & Amritha, P. S. Land use and land cover analysis in the Alappuzha District, South Kerala, India, in India III: Climate Change and Landscape Issues in India: A Cross-Disciplinary Framework, Springer, 291–307. (2025).
Li, L., Huang, X. & Yang, H. Scenario-based urban growth simulation by incorporating ecological-agricultural-urban suitability into a Future Land Use Simulation model. Cities https://doi.org/10.1016/j.cities.2023.104334 (2023).
Prayag, A. G., Zhou, Y., Srinivasan, V., Stigter, T. & Verzijl, A. Assessing the impact of groundwater abstractions on aquifer depletion in the cauvery Delta, India. Agric. Water Manag. 279, 108191. https://doi.org/10.1016/j.agwat.2023.108191 (2023).
Anjaly, C. S., Sathian, K. K., Anu, V. & Jinu, A. Assessment and mapping of water quality of a shallow aquifer near an industrial belt using Hydro-chemical parameters and irrigation water quality index. J. Agricultural Eng. (India). 60 (1), 60–73. https://doi.org/10.52151/jae2023601.1797 (2023).
Aju, C. D., Achu, A. L., Prakash, P., Raicy, M. C. & Reghunath, R. An integrated statistical-geospatial approach for the delineation of flood-vulnerable sub-basins and identification of suitable areas for flood shelters in a tropical river basin, Kerala. Geosyst. Geoenvironment. 3 (2), 100251. https://doi.org/10.1016/j.geogeo.2024.100251 (2024).
Satterthwaite, D., Mcgranahan, G. & Tacoli, C. Urbanization and its implications for food and farming,. 2809–2820. https://doi.org/10.1098/rstb.2010.0136 2010. https://doi.org/10.1098/rstb.2010.0136
Prasood, S. P., Mukesh, M. V., Rani, V. R., Sajinkumar, K. S. & Thrivikramji, K. P. Urbanization and its effects on water resources: Scenario of a tropical river basin in South India. Remote Sens Appl https://doi.org/10.1016/j.rsase.2021.100556 (2021).
Shimod, K. P., Vineethkumar, V., Prasad, T. K. & Jayapal, G. Effect of urbanization on heavy metal contamination: a study on major townships of Kannur District in Kerala, India. Bull. Natl. Res. Cent. https://doi.org/10.1186/s42269-021-00691-y (2022).
Devi, A. & Nair, A. Effects of urbanization in a shallow coastal aquifer: an integrated GIS-based case study in Cochin, India. Groundw. Sustain. Dev. 15, 100656. https://doi.org/10.1016/j.gsd.2021.100656 (Aug. 2021).
Salim, M. Z. et al. A comprehensive review of navigating urbanization induced climate change complexities for sustainable groundwater resources management in the Indian Subcontinent. Groundw. Sustainable Dev. 25, 101115. https://doi.org/10.1016/j.gsd.2024.101115 (2024).
Fan, C. & Wang, Z. Spatiotemporal characterization of land cover impacts on urban warming: A Spatial autocorrelation approach. Remote Sens. (Basel). 12 (10), 1–17. https://doi.org/10.3390/rs12101631 (2020).
Digra, M., Dhir, R. & Sharma, N. Land use land cover classification of remote sensing images based on the deep learning approaches: a statistical analysis and review. Arab. J. Geosci. https://doi.org/10.1007/s12517-022-10246-8 (2022).
Kumar, N. V., Mathew, S. & Swaminathan, G. Analysis of groundwater for potability from Tiruchirappalli City using backpropagation ANN model and GIS. J. Environ. Prot. (Irvine Calif). 01 (02), 136–142. https://doi.org/10.4236/jep.2010.12018 (2010).
Tran, D. D. et al. Environmental pressures on livelihood transformation in the Vietnamese Mekong delta: implications and adaptive pathways. J. Environ. Manage. 377, 124597. https://doi.org/10.1016/j.jenvman.2025.124597 (2025).
Tian, J. et al. Spatiotemporal monitoring of water storage in the North China plain from 2002 to 2022 based on an improved GRACE downscaling method. J. Hydrology: Reg. Stud. 59, 102370. https://doi.org/10.1016/j.ejrh.2025.102370 (2025).
Sanad, H. et al. Ecological and Health Risk Assessment of Heavy Metals in Groundwater within an Agricultural Ecosystem Using GIS and Multivariate Statistical Analysis (MSA): A Case Study of the Mnasra Region, Gharb Plain, Morocco. Water. https://doi.org/10.3390/w16172417 (2024).
Saranya, T. & Saravanan, S. A comparative analysis on groundwater vulnerability models—fuzzy DRASTIC and fuzzy DRASTIC-L. Environ. Sci. Pollut. Res. 29, 86005–86019. https://doi.org/10.1007/s11356-021-16195-1 (2022).
Subbarayan, S., Thiyagarajan, S., Karuppanan, S. & Panneerselvam, B. Enhancing groundwater vulnerability assessment: comparative study of three machine learning models and five classification schemes for Cuddalore district. Environ. Res. https://doi.org/10.1016/j.envres.2023.117769 (2023).
Fallahzadeh, R. A. et al. Spatial distribution and health risk assessment of nitrate in drinking water: A case study in the central plateau of Iran. J. Environ. Health Sustain. Dev. (2024).
Ayadi, Y. et al. Groundwater potential recharge assessment in Southern mediterranean basin using GIS and remote sensing tools: case of Khalled-Teboursouk basin, karst aquifer. Appl. Geomatics. 16 (3), 677–693 (2024).
Sivakumar, V. et al. An integrated approach for an impact assessment of the tank water and groundwater quality in Coimbatore region of South India: implication from anthropogenic activities. Environ. Monit. Assess. 195, 88 (2023).
Ngernkerd, P., Choowong, M., Choowong, N. & Surakiatchai, P. Late pleistocene climate variation on the Khorat Plateau, Northeastern Thailand inferred from the remnants of sand dunes, (2021).
Sheikh Sayed, R. et al. (n.d.). Technological and Sustainable Approaches to Groundwater Resource Assessment and Management in the Context of Urban Expansion: A Case Study in Keraniganj, Bangladesh.
Jahanshahi, A., Booij, M. J., Patil, S. D. & Gupta, H. Impact of land use land cover change on catchment hydrological response in 576 Iranian catchments. J. Arid Environ. 231, 105463. https://doi.org/10.1016/j.jaridenv.2025.105463 (2025).
Li, X. et al. Identifying the Spatial pattern and driving factors of nitrate in groundwater using a novel framework of interpretable stacking ensemble learning. Environ. Geochem. Health. https://doi.org/10.1007/s10653-024-02201-1 (2024).
Ransom, K. M., Nolan, B. T., Stackelberg, P. E., Belitz, K. & Fram, M. S. Machine learning predictions of nitrate in groundwater used for drinking supply in the conterminous United States. Sci. Total Environ. https://doi.org/10.1016/j.scitotenv.2021.151065 (2022).
Li, Z. Extracting Spatial effects from machine learning model using local interpretation method: an example of SHAP and XGBoost. Comput. Environ. Urban Syst. 96, 101845 (2022).
Wang, H., Liang, Q., Hancock, J. T. & Khoshgoftaar, T. M. Feature selection strategies: a comparative analysis of SHAP-value and importance-based methods. J. Big Data. 11 (1), 44 (2024).
Rohde, M. M. et al. A machine learning approach to predict groundwater levels in California reveals ecosystems at risk. Front. Earth Sci. (Lausanne). 9, 784499 (2021).
Aher, S., Deshmukh, K., Gawali, P., Zolekar, R. & Deshmukh, P. Hydrogeochemical characteristics and groundwater quality investigation along the basinal cross-section of Pravara River, Maharashtra, India. J. Asian Earth Sciences: X. 7, 100082. https://doi.org/10.1016/j.jaesx.2022.100082 (2022).
Yang, S. et al. Spatial mapping and prediction of groundwater quality using ensemble learning models and Shapley additive explanations with Spatial uncertainty analysis. Water 16 (17), 2375. https://doi.org/10.3390/w16172375 (2024).
Bewket, W. & Sterk, G. Farmers’ participation in soil and water conservation activities in the Chemoga Watershed, Blue Nile Basin. Ethiopia. Land Degrad. Dev. https://doi.org/10.1002/ldr.492 (2002).
Prajapati, G. S., Rai, P. K., Mishra, V. N., Singh, P. & Shahi, A. P. Remote sensing-based assessment of waterlogging and soil salinity: A case study from Kerala, India. Results Geophys. Sci. 7, 100024. https://doi.org/10.1016/j.ringps.2021.100024 (2021). February.
Ayalew, S. E., Niguse, T. A. & Aragaw, H. M. Hydrological responses to historical and predicted land use/land cover changes in the Welmel watershed, Genale Dawa Basin, ethiopia: implications for water resource management. J. Hydrol. Reg. Stud. 52, 101709. https://doi.org/10.1016/j.ejrh.2024.101709 (2024).
Chen, D., Elhadj, A., Xu, H., Xu, X. & Qiao, Z. A study on the relationship between land use change and water quality of the Mitidja watershed in Algeria based on GIS and RS. Sustain. https://doi.org/10.3390/SU12093510 (2020).
Halder, S. et al. Understanding hydrological responses through LULC analysis and predictive modelling (MLPNN-MC Model): A study of Bandu Sub-watershed (India) over three decades. Artif. Intell. Geosci. 6 (2), 100152. https://doi.org/10.1016/j.aiig.2025.100152 (2025).
Census of India. Census of India 2011 District Census Handbook Ernakulam, p. 516, (2011).
Dash, S. S. & Maity, R. Effect of climate change on soil erosion indicates a dominance of rainfall over LULC changes. J. Hydrol. Reg. Stud. 47, 101373. https://doi.org/10.1016/j.ejrh.2023.101373 (2023).
Liu, S., Wang, L. & Guo, C. Heavy metal pollution and ecological risk assessment in brownfield soil from Xi’an, China: An integrated analysis of man land interrelations. PLoS One. 15, e024139 (2020).
Hao, Z. et al. 2025. Dynamic soil erosion in response to LULC changes in mountainous areas of southwest China over the last 40 years: A case study of the Erhai Basin in Yunnan province, Environmental and Sustainability Indicators. 27: 100755. https://doi.org/10.1016/j.indic.2025.100755 2025 https://doi.org/10.1016/j.indic.2025.100755
Mechal, A., Fekadu, D. & Abadi, B. Multivariate and water quality index approaches for Spatial water quality assessment in lake Ziway, Ethiopian rift. Water Air Soil. Pollut. 235 (1), 78. https://doi.org/10.1007/s11270-023-06882-9 (2024).
Santos, R. S. S. et al. Groundwater contamination in a rural municipality of Northeastern brazil: application of Geostatistics, Geoprocessing, and geochemistry techniques. Water Air Soil. Pollut. 235 (3), 179 (2024).
The, S., Journal, G. & Mar, N. Interdependent urbanization in an urban world: an historical overview, 164: 85–95, (2015).
Lekshmi, A. & Lancelet, P. T. Trend of urbanisation in Ernakulam with respect to Kerala. J. Global Resour. 5 (02), 41–48 (2019).
Liu, W., Zhang, L., Hu, X., Meng, Q. & Qian, J. International Journal of Applied Earth Observation and Geoinformation Nonlinear effects of urban multidimensional characteristics on daytime and nighttime land surface temperature in highly urbanized regions: A case study in Beijing China.. Int. J. Appl. Earth Observation Inf. 132, 1–12 (2024).
Acknowledgements
The authors would like to acknowledge Karunya Institute of Technology and Sciences for providing the required facilities and logistical support during this research. We are very grateful to the anonymous reviewers for their comments and time on our paper.
Funding
The work of C-HH was supported by the National Research Foundation of Korea (NRF) funded by the Korean Government (MSIT; RS-2025-00555756) and the Ministry of Education (RS-2018-NR031078).
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A.K. designed the study, carried out the data collection, performed LULC classification, groundwater quality analysis, and prepared the initial draft of the manuscript.S.G. supervised the research, contributed to the conceptualization, methodology development, geospatial and hydrochemical interpretation, and thoroughly revised and edited the manuscript.G.P.A. assisted in data interpretation, CA–Markov modelling, and contributed to the refinement of the results and discussion.S.K.J. supported the statistical analyses, machine-learning modelling, and validation procedures.C.H.H. contributed to the methodological framework, interpretation of findings, and critical revision of the manuscript for intellectual content.All authors reviewed the manuscript and approved the final version.
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K, A., Gautam, S., Prince Arulraj, G. et al. Forecasting land-use and land-cover change for groundwater sustainability in the Muvattupuzha basin using CA-Markov (2033–2050). Sci Rep (2026). https://doi.org/10.1038/s41598-026-38961-2
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DOI: https://doi.org/10.1038/s41598-026-38961-2