Table 1 Input parameters and calculated characteristics of excitons, their interactions, and the biexciton.
MoSe2 | MoS2 | WS2 | WSe2 | |
---|---|---|---|---|
μr (m0)33 | 0.350 | 0.275 | 0.175 | 0.200 |
r0 (Å)33 | 39 | 34 | 34 | 45 |
Freestanding MLs | ||||
Eb (meV) | 620 | 644 | 566 | 481 |
ax (Å) | 8.38 | 8.96 | 11.48 | 12.11 |
\({U}_{\Gamma -\Gamma }^{ex}\) (\({E}_{b}{a}_{x}^{2}\)) | 2.043 | 2.173 | 2.341 | 2.187 |
\({U}_{{\Gamma }_{2}-{\Gamma }_{3}}^{ex}\) (\({E}_{b}{a}_{x}^{2}\)) | 0.952 | 0.863 | 0.602 | 0.539 |
\({{{{\mathcal{E}}}}}_{0}\) (meV) | 64.9 | 53.4 (6012) | 18.5 | 12.9 |
hBN encapsulated MLs | ||||
κ33 | 4.4 | 4.45 | 4.35 | 4.5 |
Eb (meV) | 226 (23133) | 215 (22133) | 174 (18033) | 157 (16732) |
ax (Å) | 10.38 | 11.53 | 15.39 | 15.69 |
\({{{{\mathcal{E}}}}}_{0}\) (meV) | 24.0 (2127) | 13.2 | 1.5 | 1.4 (16–1718) |