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WATER OXIDATION

Heterogeneous electrocatalysis goes chemical

Nature Catalysis volume 4, pages 4–5 (2021)Cite this article

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Despite over a century of research to understand heterogeneous electrocatalysis, the precise mechanisms of action remain poorly understood. Now, it is proposed that the oxygen evolution reaction on IrOx is driven by changes in the redox state of the Ir–O active sites, rather than by changes in the interfacial electric field.

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Fig. 1: Heterogeneous water oxidation via surface chemical reactions.

References

  1. Guidelli, R. et al. Pure Appl. Chem. 86, 245–258 (2014).

    Article  CAS  Google Scholar 

  2. Boettcher, S. W. et al. ACS Energy Lett. https://doi.org/10.1021/acsenergylett.0c02443 (2020).

  3. Nong, H. N. et al. Nature 587, 408–413 (2020).

    Article  CAS  Google Scholar 

  4. Burke, M. S., Enman, L. J., Batchellor, A. S., Zou, S. & Boettcher, S. W. Chem. Mater. 27, 7549–7558 (2015).

    Article  CAS  Google Scholar 

  5. Grimaud, A., Hong, W. T., Shao-Horn, Y. & Tarascon, J.-M. Nat. Mater. 15, 121–126 (2016).

    Article  CAS  Google Scholar 

  6. Francàs, L. et al. Nat. Commun. 10, 5208 (2019).

    Article  Google Scholar 

  7. Corrigan, D. A. J. Electrochem. Soc. 134, 377 (1987).

    Article  CAS  Google Scholar 

  8. Surendranath, Y., Kanan, M. W. & Nocera, D. G. J. Am. Chem. Soc. 132, 16501–16509 (2010).

    Article  CAS  Google Scholar 

  9. Pearce, P. E. et al. Chem. Mater. 31, 5845–5855 (2019).

    Article  CAS  Google Scholar 

  10. Jackson, M. N. & Surendranath, Y. Acc. Chem. Res. 52, 3432–3441 (2019).

    Article  CAS  Google Scholar 

  11. Warburton, R. E. et al. J. Am. Chem. Soc. 142, 20855–20864 (2020).

    Article  CAS  Google Scholar 

Download references

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Authors and Affiliations

  1. The Department of Chemistry and Biochemistry and the Oregon Center for Electrochemistry, University of Oregon, Eugene, OR, USA

    Shannon W. Boettcher

  2. The Department of Chemistry, Massachusetts Institute of Technology, Cambridge, MA, USA

    Yogesh Surendranath

  3. Center for Interfacial Ionics, Eugene, OR, USA

    Shannon W. Boettcher & Yogesh Surendranath

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  1. Shannon W. Boettcher
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  2. Yogesh Surendranath
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Correspondence to Shannon W. Boettcher or Yogesh Surendranath.

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The authors declare no competing interests.

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Boettcher, S.W., Surendranath, Y. Heterogeneous electrocatalysis goes chemical. Nat Catal 4, 4–5 (2021). https://doi.org/10.1038/s41929-020-00570-1

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