Fig. 3
From: Bifurcation of self-assembly pathways to sheet or cage controlled by kinetic template effect
QASAP data for the self-assembly of the (X−)@[Pd214]4+ cage. The self-assembly was conducted from 1 and [PdPy*4](OTf)2 in CD3NO2 at 298 K with and without NO3−. a Existence ratios of the substrates and the products for the self-assembly of the cage without NO3−. [1]0 = 2.0 mM, [Pd]0 = 1.0 mM. b Existence ratios of the substrates and the products for the self-assembly of the cage with NO3−. [1]0 = 2.0 mM, [Pd]0 = 1.0 mM, [NO3−]0 = 2.0 mM. c An n–k plot for the self-assembly of the cage without NO3−. d An n–k plot for the self-assembly of the cage with NO3−. Error bars indicate the standard errors of the means of the existence ratios (a and b) and the (〈n〉, 〈k〉) values (c and d). The (n, k) value for Pda1bPy*c indicates as (a, b, c)
