Fig. 7
From: Bifurcation of self-assembly pathways to sheet or cage controlled by kinetic template effect
NASAP data for the self-assembly of the [Pd214]4+ cage. The self-assembly from 1 and [PdPy*4](OTf)2 in CD3NO2 at 298 K with NO3− was simulated. a The five reaction types in the network model of the self-assembly. Typical examples are shown in each type. The template anions encapsulated are omitted for clarity. A full network is shown in Supplementary Fig. 22. b Existence ratios of the substrates and the products with time. c Experimental and simulated n–k plots. d Experimental and simulated (〈n〉, 〈k〉) values with time. e Time variation of major species by simulation and a list of the rate constants found by NASAP. (a, b, c) indicates [Pda1bPy*c]2a+. The (n, k) value of [Pda1bPy*c]2a+ is also indicated in red
