Fig. 3: Characterization of the resulting PEG-b-PDAAM block copolymer.

1H NMR spectrum (a) and GPC (b) of the product at the steady state for the CSTR–BZ–PISA of PEG-b-PDAAM with a residence time (τ) of 120 min (sampled out at 180 min) and monomer/RAFT ratio of concentration = 400 at 1.1% w/w solid content. c Dynamic DAAM conversion versus time plot by UV–vis spectra for three experiments with the same theoretical target DP (400) and residence times of 40, 90, and 120 min, respectively.