Fig. 6: Representative examples for trajectories exhibiting trapping near junctions at \(E=34\) kcal mol\({}^{-1}\).
From: Stable chaos and delayed onset of statisticality in unimolecular dissociation reactions
a Frequency ratios \({f}_{1}\) (blue) and \({f}_{2}\) (red) versus time of three sample trajectories that dissociate between \((3,5,4.5)\) ps. The trajectories correspond to \(\epsilon =0.1\) (blue arrow), \(\epsilon =0.4\) (green arrow), and \(\epsilon =1.0\) (orange arrow). b Data in a shown in the frequency ratio space during the trapping events. c Fast Lyapunov indicator (FLI) as a function of time for the three sample trajectories. d, e, and f show the corresponding plots for long lifetime trajectories.
