Table 1 Photophysical parameters for photoluminescence in crystals at RT by excitation at 280 nma.
Bulk crystalsb | Nanocrystalse | |||||
---|---|---|---|---|---|---|
λmaxlum (nm) | Φ (%)c | τ (µs)d | λmaxlum (nm) | Φ (%)f | τ (µs)g | |
DT4 | 378 (minor) | 2h | 0.09 (0.96)7.6 (0.04) | 736 | 31 | 11 |
638 (major) | 56h | 0.06 (–0.76)9.8 (1.0) | ||||
DT5 | 377 (major) | 10h | 3.5 (0.65)6.5 (0.35) | 736 | 44 | 14 |
630 (minor) | 3h | 4.5 (–0.28)23 (1.1) | ||||
DT6 | 738 | 75 | 12 | 727 | 69 | 15 |