Fig. 3: Reaction scope of N- and S-directed borylation of terminal alkenes.

^aReactions were performed using 1 (0.2 mmol), 2a (2.0 equiv, 1.0 M in DCM), A5 (2.0 equiv) in DCM (1.0 mL) under N₂ atmosphere, 0 °C. ^bYield of isolated product. ^c2a (1.1 equiv, 1.0 M in DCM), A5 (1.1 equiv) in DCM (1.0 mL), 0 °C.