Table 2 Electrochemical performance comparation of cathode materials for SIBs and PIBs
From: Covalent organic framework-based cathodes for beyond lithium-ion batteries
Battery type/Metal type | Materials | Building blocks | Active materials and cathode proportion | Initial capacity (CC/DC/CD) | Cycling stability (RC/CD/CN) | Voltage (V) | Ref. |
|---|---|---|---|---|---|---|---|
SIBs | TAPB-NDA COF | 1,3,5-tris(4-aminophenyl)benzene (TAPB) and 1,4,5,8-naphthalene tetracarboxylic dianhydride (NDA) | (COF: CNT = 2:1) with Super P, and CMC- SBR binder at a weight ratio of 75:15:10 | −/136.7/0.025 A g−1 | −/0.3 A g−1/1000 | 1.5–3.5 | |
SIBs | Bipolar porous organic electrode (BPOE) | p-dicyanobenzene | active material (70 wt.%), carbon black (20 wt.%), and CMC (10 wt.%) | −/~120/0.1 A g−1 | −/1.0 A g−1/7000 | 1.3–4.1 | |
SIBs | TQBQ-COF | tetraminophenone (TABQ) and cyclohexanehexaone (CHHO) | 50 wt% TQBQ-COF powders, 40 wt% Super P and 10 wt% PVDF | −/~300/0.1 A g−1 | 213.6/1.0 A g−1/1000 | 1.0–3.6 | |
PIBs | PT-Si-COF-Co | Pc(OH)8Co and silica gel | 60 wt% active materials, 30 wt% Super P and 10 wt % PVDF binder | −/386/40 mA g−1 | 118/1 A g−1/5000 | 0.005–3.0 | |
PIBs | DAAQ-COF | 2,6-diaminoanthraquinone (DAAQ) and 1,3,5-triformylphloroglucinol (TFP) | 60 wt % Active material (DAAQ-COF: CNT = 2:1 first), 30 wt% CNT dispersion (the solid content of CNTs is 20 wt%), and 10 wt% PVDF | −/157.7/0.1 A g−1 | ~130/0.5 A g−1/500 | 0.8–2.8 | |
PIBs | TCNQ-CTF | tetracyanoquinodimethane (TCNQ) | CTFs, acetylene black, PVDF with a mass ratio of 7:2:1 | −/161/0.1 A g−1 | 85/5 A g−1/1000 | 1.0–3.9 | |
PIBs | Poly (pentacenetetrone sulfide) (PPTS) | Chlorobenzene and pyromellitic dianhydride | PPTS with Super P and CMC of 5:4:1 | −/~260/0.1 A g−1 | 190/5 A g−1/3000 | 0.1–3.2 | |
PIBs | Perylene | Perylene-3,4,9,10-tetracarboxylic dianhydride (PTCDA) | Active materials with carbon black, and CMC at a weight ratio of 8:1:1 | −/126/0.1 A g−1 | 98/1 A g−1/1000 | − | |
SIBs | Inorganic | NaFe0.2Mn0.4Ni0.4O2 | active material, acetylene black, and PVDF in a weight ratio of 75:15:10 | −/133/0.05 C | 130/0.05 C/30 | 2.0–4.3 | |
PIBs | Inorganic | K3V2(PO4)3/C nanocomposites | active material, super-P, and PVDF in a weight ratio of 80: 10: 10 | 77/54/20 mA g−1 | 52/20 mA g−1 /100 | 2.5–4.3 |
