Table 1 Results of non-linear least-squares curve fitting analysis for the Pb and Hg L3 edge spectra of the PbS and PbS:Hg QDs adsorbed on TiO2 with different HgCl2 concentration. Bulk PbS and HgS are references. CN, R and σ2 represent coordination number, interatomic distance and Debye-Waller factor
From: Quantum-Dot-Sensitized Solar Cell with Unprecedentedly High Photocurrent
Bond | CN | R (Å) | σ2(10−3×Å2) | |
|---|---|---|---|---|
Bulk PbS | (Pb-S) | 6 | 2.869 | 17.58 |
0 mmol | (Pb-S) | 3.07 | 2.796 | 26.30 |
2 mmol | (Pb-S) | 2.95 | 2.780 | 18.77 |
4 mmol | (Pb-S) | 3.16 | 2.772 | 20.88 |
6 mmol | (Pb-S) | 1.94 | 2.755 | 15.88 |
8 mmol | (Pb-S) | 2.64 | 2.732 | 16.42 |
Bulk HgS | (Hg-S) | 4 | 2.492 | 10.72 |
2 mmol | (Hg-S) | 3.74 | 2.384 | 4.95 |
4 mmol | (Hg-S) | 4.05 | 2.359 | 6.78 |
6 mmol | (Hg-S) | 3.73 | 2.369 | 5.15 |
8 mmol | (Hg-S) | 3.96 | 2.373 | 6.33 |
