Table 1 Physicochemical parameters for the aqueous three-phase systems

From: Molecular Aggregates in Stable Aqueous Three-Phase Surfactant Systems and Their use in Producing CdS Nanowires

Samples

Top phase

Middle phase

Bottom phase

Texapon N 70 /C 14 DMAO/HCOOH

discs

lamellas

discs

(cN70 = 26.5 mM, cC14DMAO = 100 mM, 25°C)

(L1')

(Lα)

(L1')

nN70/nC14DMAO

0.25

0.31

0.32

Density (g cm−3)

0.893

1.050

1.165

Phase volume fraction (%)

31

40

29

LA/C 12 EO 4

vesicles

sponge structures

discs

(WT = 23%, RLA = 0.25, 25°C)†

(Lα')

(L3)

(L1')

Density (g cm−3)

0.828

0.985

1.021

Phase volume fraction (%)

36

49

15

SL/TTABr

lamellas

threadlike micelles

vesicles

(cT = 100 mM, RnSL = 0.395, 20°C)‡

(Lα)

(L1)

(Lα')

nSL/nTTABr

0.62

0.57

0.82

Density (g cm−3)

0.718

0.814

1.216

Phase volume fraction (%)

5

47

48

  1. †WT is the mass fraction of the total surfactant in solution; RLA is the mass fraction of LA to total surfactant composition (RLA = wLA/(wLA + wC12EO4)).
  2. ‡cT is the molar concentration of the total surfactant in the solution; RnSL is the mole ratio of SL to the surfactant mixture (RnSL = nSL/(nSL + nTTABr)).