Table 1 Electrodeposition parameters. PdCu NWs with pre-contoured shapes were electrodeposited inside the nanochannel (~70 nm in diameter) of the AAO under various Pd:Cu cations molar ratio and pH value of the electrolyte and applied voltage
Shapes of PdCu NWs | Pd:Cu cations molar ratio | Electrolyte pH | Applied voltage (volt) |
---|---|---|---|
Smooth | 1 ~ 1.5 | 7 ~ 8 | 1.2 ~ 2.2 |
Random-gapped | 0.9 | 5 ~ 6 | 1.3 ~ 1.8 |
Random-chapped | 1 ~ 2 | 7 ~ 9 | 2.0 ~ 2.8 |
Periodic-gapped | 1 | 4 ~ 6 | 1.4 ~ 2.6 |