Table 4 Tight-Binding Parameters for Monolayer of VA Elements (eV).

Element	N	P		As		Sb		Bi
Element	N	No SOC	SOC	No SOC	SOC	No SOC	SOC	No SOC	SOC
ε_s	−6.80	−5.02	−5.02	−4.90	−7.53	−5.49	−6.79	−7.09	−8.89
ε_p	−1.67	−0.565	−0.565	−0.275	−0.452	−0.252	−0.613	−0.105	−0.563
γ_ss	−1.49	−1.07	−1.08	−0.351	−1.22	−0.448	−0.985	−0.0515	−0.864
γ_sp	4.76	2.89	2.89	1.98	2.72	1.85	2.20	1.61	1.99
γ_ppσ	−5.94	−3.34	−3.34	−2.91	−2.77	−2.29	−2.26	−2.04	−2.02
γ_ppπ	1.56	0.767	0.767	0.684	0.606	0.557	0.472	0.394	0.395
γ′_ss	0.216	0.260	0.261	0.0986	−0.0529	0.0490	−0.0735	−0.0186	−0.124
γ′_sp	−0.0235	−0.0562	−0.0562	−0.0637	0.179	−0.0384	0.0280	−0.0200	−0.124
γ′_ppσ	1.38	1.15	1.15	0.858	0.786	0.653	0.646	0.535	0.551
γ′_ppπ	−0.499	−0.377	−0.377	−0.233	−0.174	−0.162	−0.130	−0.109	−0.140
λ_I/10⁻³	—	—	−0.141	—	0	—	1.97	—	0
λ_R/10⁻²	—	—	0.406	—	0	—	0.278	—	0
λ_OS	—	—	−0.0106	—	−0.285	—	−0.299	—	−0.630

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