Table 1 Segregation of potassium, sodium, tantalum and niobium and the growth temperatures of K1−xNaxTa1−yNbyO3crystals.

From: Origin of giant piezoelectric effect in lead-free K1−xNaxTa1−yNbyO3 single crystals

Composition of the KNTN crystal

K/Na in the melt

Ta/Nb in the melt

K0.30Na0.70Ta0.37Nb0.63O3

75:25

10:90

K0.36Na0.64Ta0.40Nb0.60O3

75:25

15:85

K0.39Na0.61Ta0.42Nb0.58O3

75:25

18:82

Segregation of K

Segregation of Na

Segregation of Ta

Segregation of Nb

Tg(°C)

0.400

2.800

3.700

0.700

1193.0

0.480

2.560

2.667

0.706

1245.0

0.520

2.440

2.333

0.707

1277.5