Table 1 NMR data for penicophenones A (1) and B (2)a.
From: Novel small molecule 11β-HSD1 inhibitor from the endophytic fungus Penicillium commune
no. | 1 | 2 | ||
|---|---|---|---|---|
δH | δC | δH | δC | |
1 | 157.3 | 111.2 | ||
2 | 118.2 | 160.9 | ||
3 | 7.28 s | 130.9 | 113.8 | |
4 | 114.1 | 160.6 | ||
5 | 161.9 | 116.3 | ||
6 | 110.1 | 7.58 s | 131.1 | |
7 | α 2.69 dd (16.8, 6.4) β 2.20 dd (16.8, 2.8) | 24.5 | 3.75 s | 21.54 |
8 | 1.88 m | 34.5 | 117.4 | |
9 | 102.9 | 114.9 | ||
10 | α 1.09 dd (12.6, 11.3) β 2.13 ddd (12.6, 4.8, 1.7) | 40.8 | 6.46 s | 100.8 |
11 | 4.00 m | 65.3 | 148.1 | |
12 | α 0.99 dt (12.1, 11.6) β 1.81 m | 43.1 | 141.8 | |
13 | 3.61 dqd (12.5, 6.3, 2.1) | 67.7 | 6.51 s | 114.9 |
14 | 1.94 s | 15.4 | 203.2 | |
15 | 204.8 | 2.50 s | 26.3 | |
16 | 2.33 s | 26.3 | 2.10 s | 16.1 |
17 | 0.73 d (7.1) | 15.4 | 3.52 s | 56.74 |
18 | 0.87 d (6.3) | 21.7 | 3.66 s | 55.5 |
