Table 1 Ni-MOF-74 obtained with DGC and CS synthesis conditions and their surface areas and yields.

From: An Efficient Synthesis Strategy for Metal-Organic Frameworks: Dry-Gel Synthesis of MOF-74 Framework with High Yield and Improved Performance

Material

Method and Solvents

Temperature (°C)

Time (h)

BET surface area (m2/g)

Yield

Ni-MOF-74(DGC)

DGC (TW)

110

72

1350

90.1%

Ni-MOF-74(CS)

CS (TW)

110

72

1029

65.2%

Ni-MOF-74(DGC)

DGC (TW)

110

48

1291

89.3%

Ni-MOF-74(DGC)

DGC (TW)

110

24

1049

87.0%

Ni-MOF-74

DGC (TW)

110

12

1041

82.1%

Ni-MOF-74(DGC)

DGC (DEW)

100

24

1063

72.1%

Ni-MOF-74(CS)

CS (DEW)

100

24

983

50.2%

  1. DGC: Dry-gel conversion; CS: conventional synthesis; TW: THF + water (1:1).
  2. DEW: DMF + ethanol + water (1:1:1).