Table 1 Redox potentials and spin Hamiltonian parameters for LPMOs and flavoenzymes.

From: Single-domain flavoenzymes trigger lytic polysaccharide monooxygenases for oxidative degradation of cellulose

 

E°′ [mV/SHE]

gx

gy

gz

AzCu [10−4 cm−1]

reference

PaAA9E

+155 (pH 5)

2.054

2.054

2.263

147

this work

PaAA9H

+326 (pH 5)

2.052

2.052

2.257

154

this work

TaAA9A

n.d.

2.06

2.06

2.27

153

5

NcAA9C

+224

n.d.

n.d.

2.267

152

31

BaAA10A

+275/+370

n.d.

n.d.

2.25

135

42

BlAA10A

n.d.

2.038

2.108

2.262

125

43

SmAA10A

n.d.

2.039

2.116

2.260

116

43

ScAA10B

+251

2.020

2.090

2.270

158

43

TfAA10B

n.d.

2.018

2.103

2.262

156

43

ScAA10C

+242

2.015

2.102

2.267

153

43

SmAA10A

+275

n.d.

n.d.

n.d.

n.d.

44

AoAA11

n.d.

2.03

2.10

2.28

147

45

AnAA13

n.d.

2.047

2.077

2.259

151

11

AAQO1 (FAD)

+86 (pH 5)

    

this work

GDH (FAD)

+171 (pH 5)

    

this work

TvCDH (FAD) TvCDH (haem)

−163 (pH 3) −40 (pH 3)

    

46

NcCDHIIA (haem)

+99 (pH 6)

    

23

NcCDHIIB (haem)

+93 (pH 6)

    

23

PcCDH (haem)

+130 (pH 7)

    

47

Back to article page