Table 2 J(J + 1) power-series expansion coefficients (in cm−1) of upper-state term values in 27 substates of the C−N stretching band of CH3NH2.
Substate (υt St−i K) | a 0 | a 1 | a2 × 106 | a3 × 1010 |
|---|---|---|---|---|
(0 Aa 0) * | 1044.912526(461) | 0.732866(11) | −10.72(8) | 44.1(16) |
(0 Aa 1+) | 1047.66065(167) | 0.725175(4) | −3.92(26) | 27.3(4) |
(0 Aa 1−) | 1047.662408(196) | 0.738380(3) | −3.34(1) | −5.0(1) |
(0 Aa 2+) | 1056.257642(711) | 0.731710(12) | 5.73(6) | −29.0(9) |
(0 Aa 2−) | 1056.254285(389) | 0.731812(7) | −2.63(3) | 1.1(4) |
(0 Aa 3+) | 1069.565927(15) | 0.731614(0) | −0.31(1) | −5.5(0) |
(0 Aa 3−) | 1069.566059(76) | 0.731610(1) | −0.28(1) | 5.9(1) |
(0 Aa 4) | 1087.76225(210) | 0.730430(40) | −1.69(20) | −0.2(3) |
(0 Aa 5) | 1112.580226(61) | 0.731490(1) | −0.84(0) | −0.2(0) |
(0 Aa 6) | 1142.383547(391) | 0.731342(7) | −1.01(3) | 0.4(2) |
(0 Aa 7) | 1176.989660(29) | 0.7314660(0) | −1.02(0) | 0 |
(0 Aa 8) | 1218.14342(465) | 0.730775(22) | ||
(0 Aa 11) | 1372.109149(0) | 0.730418(0) | ||
(0 Ea 0)* | 1045.101654(472) | 0.731802(12) | −10.24(6) | 34.2(9) |
(0 Ea 1) | 1047.93850(858) | 0.737074(237) | 2.77(18) | −107(37) |
(0 Ea 2) | 1055.93689(927) | 0.730844(209) | 7.42(11) | −34(17) |
(0 Ea 3) | 1069.121205(380) | 0.731947(11) | 78(7) | 1.4(0) |
(0 Ea 4) | 1088.374933(240) | 0.731462(4) | -0.49(2) | −9(2) |
(0 Ea 5) | 1112.77336(123) | 0.731406(29) | −0.8(1) | 0 |
(0 Ea 6) | 1142.535800(365) | 0.731324(6) | ||
(0 Ea 7) | 1177.49078(396) | 0.730786(131) | ||
(0 Ea 9) | 1264.227504(0) | 0.730818(0) | ||
(0 Ea −1) | 1047.6819(828) | 0.727080(889) | −7(2) | 0 |
(0 Ea -2) | 1055.62915(546) | 0.732554(97) | −4.2(4) | 10(5) |
(0 Ea −3) | 1069.575107(628) | 0.731907(12) | −0.49(6) | 8.0(1) |
(0 Ea −5) | 1112.674698(42) | 0.731554(1) | −0.75(0) | 0 |
(0 Ea −6) | 1142.275112(0) | 0.731058(0) | ||
(0 Ea −7) | 1177.492590(0) | 0.731449(0) | ||
(0 Ea −8) | 1218.416547(0) | 0.730994(0) |
