Figure 3

Synthetic routes for group-10 metal(II) complexes 12–14 of 10-chloro-11-amino-oxoisoaporphine (Ld).
Reagents and solvents are the following: NiCl2, PdCl2, or cis-Pt(DMSO)2Cl2, methanol/CH3CN/water (v/v/v = 15:5:1) (reflux).
Synthetic routes for group-10 metal(II) complexes 12–14 of 10-chloro-11-amino-oxoisoaporphine (Ld).
Reagents and solvents are the following: NiCl2, PdCl2, or cis-Pt(DMSO)2Cl2, methanol/CH3CN/water (v/v/v = 15:5:1) (reflux).