Table 1 Electron microprobe analyses (wt% of elements with their standard deviations in parenthesis) and atomic ratios of metal phases in 126A.
Phase | n | Al | Fe | Cu | Ni | Si | Mg | Ca | Cr | Total |
|---|---|---|---|---|---|---|---|---|---|---|
khatyrkite | 16 | 47.9(2) | 0.5(1) | 51.2(5) | b.d.l. | b.d.l. | b.d.l. | b.d.l. | b.d.l. | 99.60 |
9 | 48.0(3) | 0.7(2) | 51.7(5) | b.d.l. | b.d.l. | b.d.l. | b.d.l. | b.d.l. | 100.40 | |
13 | 47.7(3) | 0.6(1) | 51.3(5) | b.d.l. | b.d.l. | b.d.l. | b.d.l. | b.d.l. | 99.60 | |
9 | 48.0(4) | 1.04(6) | 51.0(5) | b.d.l. | 0.06(2) | b.d.l. | b.d.l. | b.d.l. | 100.10 | |
5 | 48.9(5) | 1.4(1) | 50.1(8) | b.d.l. | b.d.l. | b.d.l. | b.d.l. | b.d.l. | 100.40 | |
8 | 48.2(2) | 0.9(1) | 51.0(5) | b.d.l. | b.d.l. | b.d.l. | b.d.l. | b.d.l. | 100.10 | |
11 | 48.1(4) | 1.3(2) | 50.8(9) | b.d.l. | b.d.l. | b.d.l. | 0.03(2) | b.d.l. | 100.23 | |
2 | 47.8(2) | 2.68(6) | 49.31(3) | b.d.l. | 0.16(4) | b.d.l. | 0.03(2) | 0.07(3) | 100.05 | |
2 | 48.7(5) | 2.10(3) | 49.94(9) | b.d.l. | 0.09(5) | 0.1(1) | b.d.l. | b.d.l. | 100.93 | |
2 | 48.42(5) | 2.16(7) | 49.4(9) | b.d.l. | 0.10(2) | b.d.l. | 0.05(2) | b.d.l. | 100.13 | |
2 | 47.2(1) | 1.6(2) | 50.20(3) | b.d.l. | 0.2(1) | b.d.l. | b.d.l. | b.d.l. | 99.20 | |
β-phase | 3 | 38.7(2) | 1.5(1) | 59.5(6) | b.d.l. | b.d.l. | b.d.l. | 0.03(2) | b.d.l. | 99.73 |
3 | 38.3(1) | 2.7(3) | 57.8(5) | b.d.l. | b.d.l. | b.d.l. | b.d.l. | 0.05(3) | 98.85 | |
2 | 35.9(4) | 4.23(4) | 61.2(4) | b.d.l. | b.d.l. | b.d.l. | b.d.l. | 0.07(2) | 101.40 | |
3 | 33.92(8) | 3.1(1) | 62.7(6) | b.d.l. | b.d.l. | b.d.l. | b.d.l. | 0.05(1) | 99.77 | |
2 | 35.80(5) | 2.7(3) | 60.8(1) | b.d.l. | b.d.l. | b.d.l. | 0.04(1) | b.d.l. | 99.34 | |
2 | 36.1(3) | 2.73(9) | 60.8(9) | b.d.l. | b.d.l. | b.d.l. | b.d.l. | b.d.l. | 99.63 | |
λ-phase | 4 | 55.0(4) | 30.4(6) | 14.2(3) | b.d.l. | 0.30(1) | b.d.l. | 0.03(1) | 0.16(3) | 100.09 |
i-phase I | 3 | 43.2(1) | 15.0(5) | 41.0(4) | b.d.l. | 0.14(6) | b.d.l. | 0.04(2) | 0.14(1) | 99.52 |
i-phase II | 3 | 42.0(7) | 9.4(9) | 47.3(9) | b.d.l. | 0.08(5) | 0.04(6) | b.d.l. | 0.09(3) | 98.91 |
i-phase II | 9 | 40.3(5) | 9.2(4) | 48.7(6) | b.d.l. | 0.06(3) | 0.06(6) | 0.04(1) | 0.11(2) | 98.47 |
Formulae on the basis of 100 atoms | ||||||||||
khatyrkite | 68.54 | 0.35 | 31.11 | — | — | — | — | — | 100.00 | |
68.29 | 0.48 | 31.23 | — | — | — | — | — | 100.00 | ||
68.37 | 0.42 | 31.21 | — | — | — | — | — | 100.00 | ||
68.36 | 0.72 | 30.84 | — | 0.08 | — | — | — | 100.00 | ||
69.02 | 0.95 | 30.03 | — | — | — | — | — | 100.00 | ||
68.57 | 0.62 | 30.81 | — | — | — | — | — | 100.00 | ||
68.40 | 0.89 | 30.68 | — | — | — | 0.03 | — | 100.00 | ||
68.05 | 1.84 | 29.81 | — | 0.22 | — | 0.03 | 0.05 | 100.00 | ||
68.47 | 1.43 | 29.82 | — | 0.12 | 0.16 | — | — | 100.00 | ||
68.61 | 1.48 | 29.72 | — | 0.14 | — | 0.05 | — | 100.00 | ||
67.93 | 1.11 | 30.68 | — | 0.28 | — | — | — | 100.00 | ||
β-phase | 59.81 | 1.12 | 39.04 | — | — | — | 0.03 | — | 100.00 | |
59.68 | 2.04 | 38.24 | — | — | — | — | 0.04 | 100.00 | ||
56.12 | 3.20 | 40.62 | — | — | — | — | 0.06 | 100.00 | ||
54.65 | 2.42 | 42.89 | — | — | — | — | 0.04 | 100.00 | ||
56.87 | 2.08 | 41.01 | — | — | — | 0.04 | — | 100.00 | ||
57.09 | 2.09 | 40.82 | — | — | — | — | — | 100.00 | ||
λ-phase | 72.27 | 19.29 | 7.92 | — | 0.38 | — | 0.03 | 0.11 | 100.00 | |
i-phase I | 63.44 | 10.64 | 25.57 | — | 0.20 | — | 0.04 | 0.11 | 100.00 | |
i-phase II | 62.87 | 6.80 | 30.07 | — | 0.12 | 0.07 | — | 0.07 | 100.00 | |
i-phase II | 61.40 | 6.77 | 31.51 | — | 0.09 | 0.10 | 0.04 | 0.09 | 100.00 | |
