Table 2 13C NMR for compounds 1–13 (100 MHz).
From: Flavichalasines A–M, cytochalasan alkaloids from Aspergillus flavipes
no. | 1 a | 2 a | 3 a | 4 a | 5 a | 6 a | 7 b | 8 a | 9 a | 10 a | 11 a | 12 a | 13 a |
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
1 | 175.0 | 175.8 | 175.3 | 174.9 | 175.1 | 177.6 | 174.1 | 177.6 | 176.8 | 176.7 | 175.8 | 176.6 | 176.9 |
3 | 52.7 | 52.5 | 52.6 | 52.9 | 52.55 | 52.3 | 49.7 | 52.1 | 51.9 | 52.2 | 52.3 | 52.3 | 52.4 |
4 | 48.5 | 47.9 | 47.6 | 47.7 | 48.5 | 54.4 | 50.7 | 52.9 | 52.3 | 53.6 | 51.2 | 55.2 | 56.9 |
5 | 35.8 | 35.3 | 35.3 | 35.3 | 36.2 | 36.6 | 34.8 | 36.4 | 36.4 | 36.7 | 36.3 | 36.6 | 36.7 |
6 | 141.5 | 139.4 | 140.7 | 141.8 | 143.5 | 140.9 | 139.4 | 141.0 | 141.4 | 141.5 | 142.2 | 141.3 | 141.1 |
7 | 124.9 | 128.4 | 127.2 | 126.5 | 123.2 | 126.7 | 125.4 | 127.1 | 126.3 | 126.2 | 126.3 | 126.4 | 126.6 |
8 | 47.3 | 43.7 | 46.6 | 45.6 | 44.3 | 44.6 | 43.0 | 44.1 | 44.7 | 45.5 | 44.3 | 44.2 | 43.4 |
9 | 67.9 | 68.6 | 68.0 | 67.8 | 69.2 | 69.2 | 67.6 | 69.3 | 68.9 | 66.8 | 68.0 | 67.8 | 68.5 |
10 | 49.1 | 48.8 | 49.0 | 49.1 | 48.7 | 50.0 | 48.7 | 49.6 | 49.8 | 49.4 | 49.2 | 49.9 | 50.0 |
11 | 13.8 | 13.6 | 13.6 | 13.6 | 13.8 | 13.8 | 13.1 | 13.8 | 13.8 | 13.8 | 13.9 | 13.8 | 13.8 |
12 | 20.0 | 20.1 | 19.8 | 19.9 | 20.1 | 19.8 | 19.6 | 19.8 | 19.7 | 19.8 | 19.8 | 19.8 | 19.8 |
13 | 40.3 | 46.7 | 38.0 | 39.3 | 48.3 | 125.5 | 124.2 | 125.7 | 126.3 | 126.0 | 126.5 | 125.4 | 126.0 |
14 | 149.6 | 76.2 | 82.9 | 83.9 | 82.9 | 138.0 | 135.6 | 138.1 | 136.3 | 136.4 | 136.8 | 139.1 | 138.7 |
15 | 32.7 | 39.1 | 42.0 | 41.9 | 31.8 | 38.9 | 38.8 | 39.9 | 38.2 | 38.8 | 37.6 | 37.0 | 35.0 |
16 | 38.6 | 34.5 | 23.1 | 31.1 | 29.4 | 30.2 | 28.6 | 30.8 | 36.8 | 37.3 | 33.2 | 31.1 | 32.7 |
17 | 75.6 | 72.5 | 76.4 | 81.1 | 73.0 | 71.5 | 72.1 | 70.4 | 212.7 | 212.4 | 215.4 | 74.7 | 75.6 |
18 | 211.4 | 40.2 | 67.6 | 215.5 | 103.6 | 80.2 | 73.5 | 32.8 | 76.4 | 74.6 | 77.0 | 206.2 | 210.0 |
19 | 59.4 | 36.4 | 48.0 | 53.6 | 52.6 | 79.7 | 27.3 | 19.5 | 25.5 | 34.0 | 35.9 | 41.0 | 42.8 |
20 | 74.5 | 48.1 | 73.7 | 72.7 | 77.5 | 43.8 | 33.8 | 36.7 | 36.3 | 69.1 | 67.1 | 81.0 | 74.4 |
21 | 205.3 | 208.3 | 208.0 | 205.8 | 206.5 | 212.4 | 212.0 | 213.6 | 213.2 | 209.2 | 209.2 | 207.6 | 211.6 |
22 | 25.7 | 25.7 | 25.7 | 25.7 | 25.7 | 25.8 | 24.0 | 25.7 | 25.7 | 25.7 | 25.8 | 25.7 | 25.8 |
23 | 23.9 | 23.9 | 23.8 | 23.8 | 23.8 | 23.8 | 23.5 | 23.8 | 23.8 | 23.8 | 23.9 | 23.9 | 23.9 |
24 | 22.1 | 22.2 | 22.2 | 22.1 | 22.2 | 22.2 | 21.6 | 22.2 | 22.2 | 22.1 | 22.0 | 22.1 | 22.0 |
25 | 115.7 | 27.6 | 21.0 | 21.3 | 27.4 | 16.1 | 15.5 | 15.6 | 15.2 | 15.3 | 15.4 | 15.9 | 16.8 |
OCH3 | 58.2 | 58.0 |
