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Showing 1–17 of 17 results
Advanced filters: Author: C. M. Toste Clear advanced filters

  • Transition metal catalysis is well established as an enabling tool in synthetic organic chemistry. Photoredox catalysis has recently emerged as a method to effect reactions that occur through single-electron-transfer pathways. Here we review the combination of the two to show how this provides access to highly reactive oxidation states of transition metals and distinct activation modes that further enable the synthetic chemist.

    • Jack Twilton
    • Chi (Chip) Le
    • David W. C. MacMillan
    Reviews
    Nature Reviews Chemistry
    Volume: 1, P: 1-19

  • Covalent inhibitors are powerful entities in drug discovery. Now the amino acid selectivity and reactivity of a diverse electrophile library have been assessed proteome-wide using an unbiased workflow. This comparative analysis and the probes described could help guide the discovery and design of covalent ligands targeting residues beyond cysteine.

    • Patrick R. A. Zanon
    • Fengchao Yu
    • Stephan M. Hacker
    ResearchOpen Access
    Nature Chemistry
    Volume: 17, P: 1712-1721

  • Theoretical studies predict that the introduction of nitrogen atoms onto cycloparaphenylene frameworks would add fascinating properties but few partially N-doped carbon nanorings have been synthesized. Here, the authors report the synthesis of a cycloparaazine, where every para-connected aromatic moiety consists of a N-heterocycle, and two other highly N-doped carbon nanorings.

    • Till Drennhaus
    • Daiki Imoto
    • Kenichiro Itami
    ResearchOpen Access
    Nature Communications
    Volume: 16, P: 1-13

    • C. DORÉE
    • J. F. MCGHIE
    Research
    Nature
    Volume: 154, P: 147-148

  • Monoborylated alkanes display diverse reactivity and broad application; however, despite an increasing number of approaches to access them, multiborylated alkanes have yet to realize their synthetic potential. This Review highlights the current state-of-the-art in approaches to and synthetic applications of multiborylated alkanes.

    • Kane A. C. Bastick
    • Dean D. Roberts
    • Allan J. B. Watson
    Reviews
    Nature Reviews Chemistry
    Volume: 8, P: 741-761

  • Heterogeneous catalysis is a diverse and highly interdisciplinary field in chemistry, which is essential in our modern society. This Review highlights how understanding the active site in catalysts will help in their rational design — an essential step in a transition to renewable energy and a circular economy.

    • Charlotte Vogt
    • Bert M. Weckhuysen
    Reviews
    Nature Reviews Chemistry
    Volume: 6, P: 89-111

  • Secondary-sphere interactions serve a fundamental role in controlling the reactivity and selectivity of organometallic and enzyme catalysts, but their study in organocatalytic systems is scarce. Now, it has been shown that the in situ secondary-sphere modification of organocatalysts combined with machine-learning techniques can uncover reaction mechanisms and streamline catalyst optimization.

    • Vasudevan Dhayalan
    • Santosh C. Gadekar
    • Anat Milo
    Research
    Nature Chemistry
    Volume: 11, P: 543-551

  • The hydration and ion pairing of metal-organic supramolecular cages plays a crucial role in their interaction with guests but is difficult to quantify with standard analysis. Here, the authors show that microwave microfluidics to measure the hydration and ion pairing of two tetrahedral metal-organic cages.

    • Angela C. Stelson
    • Cynthia M. Hong
    • Christian J. Long
    ResearchOpen Access
    Communications Chemistry
    Volume: 2, P: 1-10

  • The ocean is mitigating global warming by absorbing large amounts of excess carbon dioxide from human activities. To quantify and monitor the ocean carbon sink, we need a state-of-the-art data resource that makes data submission and retrieval machine-compatible and efficient.

    • Toste Tanhua
    • Siv K. Lauvset
    • Robert M. Key
    Comments & OpinionOpen Access
    Communications Earth & Environment
    Volume: 2, P: 1-4