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Showing 1–3 of 3 results
Advanced filters: Author: Cate S. Anstöter Clear advanced filters

  • The capture of an electron by a molecule represents one of the most fundamental chemical transformations, but its mechanism at very low energies remains unclear. Now, it is shown that low-energy electron attachment to hexafluorobenzene is mediated by a non-valence correlation-bound state of the anion.

    • Joshua P. Rogers
    • Cate S. Anstöter
    • Jan R. R. Verlet
    Research
    Nature Chemistry
    Volume: 10, P: 341-346

  • Resolving concerted nuclear and electronic motion in real-time is a primary goal in chemistry. The authors monitor nuclear and valence electronic dynamics in the excited state single-bond isomerisation of a chromophore of photoactive yellow protein, using time-resolved photoelectron imaging and electronic structure calculations.

    • Cate S. Anstöter
    • Basile F. E. Curchod
    • Jan R. R. Verlet
    ResearchOpen Access
    Nature Communications
    Volume: 11, P: 1-7

  • Photoactive biomolecules rely on chromophores whose photochemistry depends on the environment. Here, the excited state dynamics of a model for the anionic biochromophore in photoactive yellow protein is investigated by time-resolved photoelectron spectroscopy showing involvement of a non-valence state, and lack of E-Z isomerisation in the gas phase.

    • James N. Bull
    • Cate S. Anstöter
    • Jan R. R. Verlet
    ResearchOpen Access
    Nature Communications
    Volume: 10, P: 1-9