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Showing 1–2 of 2 results
Advanced filters: Author: Christopher Golz Clear advanced filters

  • The ubiquity of N-heterocyclic carbenes (NHCs) in chemical research typically arises from their potent stabilizing capabilities and role as innocent spectators to stabilize otherwise non-bottleable compounds and complexes. Here, the authors reveal how NHC coordination enables selective C(sp3)–H bond scission, unlocking well-defined tin macrocycles which contrast with the typical role of NHCs in stabilizing low-valent main group centres.

    • Jennifer Klaucke
    • Navutheya Sinthathurai
    • Malte Fischer
    ResearchOpen Access
    Nature Communications
    Volume: 16, P: 1-9

  • Synthetic methods that efficiently construct structurally diverse molecular scaffolds are attractive routes to diversely bioactive molecules. Here the authors report a method whereby common starting materials are converted to structurally and functionally diverse products by changing the catalyst ligand.

    • Yen-Chun Lee
    • Sumersing Patil
    • Herbert Waldmann
    ResearchOpen Access
    Nature Communications
    Volume: 8, P: 1-12