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Showing 201–205 of 205 results
Advanced filters: Author: D Faust Clear advanced filters
  • Strategic design and synthesis of semiconducting polymers with intrinsic ductility and/or stretchability are introduced in this review. The best polymer films show high charge mobilities over 1 cm2V−1s−1 even at 100% tensile strain. On the other hand, their mechanical properties remain inadequate, with high elastic moduli over 0.1 GPa. For semiconducting polymers to be promising candidates in applications such as wearable electronics, electronic skins, and bioelectronics, the trade-off relationship between their electronic and mechanical performance must be prevented by further developing and combining versatile and efficient approaches.

    • Tomoya Higashihara
    Reviews
    Polymer Journal
    Volume: 53, P: 1061-1071
  • This paper reviews the development of zincate-complex metathesis polymerization (ZCMP) and its application to protection-free direct synthesis of poly(3-(6-hydroxyhexyl)thiophene) as well as block copolythiophene. The modified ZCMP system using Ni(dcpe)Cl2 as a catalyst accomplished the preparation of well-defined poly(3-hexylthiophene)s (P3HTs) (Mn up to 35 000 g mol−1) with extremely low PDI (1.03∼1.11). In addition, the first example of all-conjugated block copolythiophene, P3HT-b-poly(3-octadecylthiophene), could be synthesized on the basis of the sequential monomer addition approach based on ZCMP.

    • Tomoya Higashihara
    • Eisuke Goto
    Reviews
    Polymer Journal
    Volume: 46, P: 381-390
  • Thermally stable and photosensitive polymers have been widely developed in recent years for their applications in the electronic packaging such as buffer coating, passivation layers, and insulation layers for redistribution in microelectronics due to their excellent thermal and reasonable dielectric properties. This review describes the recent progress of TSPSPs in the last decade and focuses on their design concept. After a brief introduction of the basic patterning procedure, various chemistries on the design of TSPSPs are highlighted along with two major patterning methodologies such as positive- and negative-working polymers. Furthermore, new applications of TSPSPs, such as low dielectric materials, high refractive index lenses, resists for ITO patterning, and π-conjugated polymers for organic-field effect transistors, are also introduced.

    • Mao-Chun Fu
    • Tomoya Higashihara
    • Mitsuru Ueda
    Reviews
    Polymer Journal
    Volume: 50, P: 57-76