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A new model merges behavioural science and machine learning to predict choice under risk and uncertainty. Tested on multiple large datasets, it outperforms top psychological and AI models, enabling accurate, interpretable forecasts of human decisions.

Intercalation — a cornerstone of materials science with wide-ranging applications — has now been demonstrated in a superatomic crystal. A redox-active tetracyanoethylene guest was inserted into the lattice of a material consisting of alternate layers of {Co₆Te₈} clusters and C₆₀ fullerenes, leading to a single-crystal-to-single-crystal transformation that significantly modulates the material's optical and electrical transport properties.

Recent developments in advanced light sources have made it possible to transiently alter the electronic properties of materials by exciting specific atomic vibrations in solids. This study provides a theoretical framework for these experiments.

Levantine Phoenicians made little genetic contribution to Punic settlements in the central and western Mediterranean between the sixth and second centuries bce; instead, the Punic people derived most of their ancestry from a genetic profile similar to that of Sicily and the Aegean, with notable contributions from North Africa as well.

Experimental evidence for charge coupling to ferroelectric soft mode is scarce. Here, the authors find a photogenerated coherent phonon coupling to the electronic transition above the bandgap in the van der Waals ferroelectric semiconductor NbOI2.

A simulation establishes the relationship between structural relaxation in a supercooled liquid and the low-frequency dynamics in the underlying inherent structures.

Experiments suggest that placing molecules in an infrared cavity alters their reactivity, an effect lacking a clear theoretical explanation. Here, the authors show that the key to understanding this process may lie in quantum light-matter interactions.

Technologies for profiling biological environments with high spatiotemporal resolution are in demand to enable the discovery of new targets for addressing unmet clinical needs. Now, a deep red light-mediated photocatalytic strategy for the targeted activation of aryl azides has been developed. This platform enables mapping of protein microenvironments in physiologically relevant systems.

Glasses can be divided into fragile or strong, depending on whether they show a marked dependence of their relaxation time with temperature when approaching the glass transition. Although colloidal particles have previously been found to produce only fragile glasses, here it is shown that deformable colloidal particles exhibit the same variation in fragility as that observed in molecular liquids. Colloids are easy to study, so this model should provide new insight into glass formation in molecular systems.

Rare quantum tunneling two-level systems are known to govern the glass physics at low temperatures, but it remains challenging to detect them in simulations. Ciarella et al. show a machine learning approach to efficiently identify the structural defects, allowing to predict the quantum splitting.

Singlet fission — the splitting of a singlet exciton into two triplets — is a process that could be exploited to improve the power conversion efficiency of solar cells. Spectroscopic data now suggest that coherent and incoherent mechanisms for singlet fission in crystalline hexacene coexist and occur on different timescales.

It is often assumed that systems that can be analyzed accurately via mean-field theory would not be worth looking at using quantum algorithms, given entanglement plays no key role. Here, the authors show instead that a quantum advantage can be expected for simulating the exact time evolution of such electronic systems.

Superconductivity reported in metals driven away from equilibrium via optical pumping has been proposed to arise from nonlinear coupling between electrons and optically excited phonons. The authors use an exact approach to show that here, disorder, which disfavors superconductivity, emerges even though the system is translationally invariant.

Retinoblastoma is the most frequent intraocular paediatric malignancy whose molecular basis remains poorly understood. Here, the authors perform multi-omic analysis and identify two subtypes; one in a cone differentiated state and one more aggressive showing cone dedifferentiation and expressing neuronal markers.

In atomic solids, substitutional doping is a powerful approach to modulating materials properties. Now, three substitutional mixtures of {Co₆Se₈} and {Cr₆Te₈} clusters in a crystal lattice with C₆₀ fullerenes have been prepared. At two Co:Cr mixing ratios, the solid solutions showed particularly high electrical conductivities and low activation barriers for electron transport, owing to their structural heterogeneity.

Strong many-body Coulomb interactions allow for bound two- and three-body excitonic states to form in monolayer transition metal dichalcogenides, but it is now shown that such interactions are strong enough to create four-body biexcitonic states.

Intuition suggests that the occurrence of large quantum fluctuations should prevent a material from forming a glass by enabling its atoms to rearrange into a lower-energy ordered state. But new simulations suggest the opposite could be true, with fluctuations sometimes enhancing glass formation.

Electronic bandgap tuning in semiconductors enables key functionalities in solid-state devices. Here, the authors present a strategy to control the bandgap of atomically thin WS₂ and WSe₂semiconductors via manipulation of the surrounding dielectric environment rather than by modifications of the materials themselves.

Exciton-polaritons are part-light part-matter states in semiconductors. Here the authors leverage momentum-resolved optical microscopy to image ballistic and diffusive propagation of exciton-polaritons on femtosecond scales.

A new type of exciton is observed in transition-metal dichalcogenide heterobilayers that is indirect in both real space and momentum space. It consists of a paired electron in MoS₂ at the K point and hole spread across MoS₂ and WSe₂ at the Γ point.

Despite recent progress in the synthesis and characterization of molybdenum disulphide, little is yet known about its microstructure. Using refined chemical vapour deposition synthesis, high-quality crystals of monolayer molybdenum disulphide have now been grown. Single-crystal islands and polycrystals containing tilt and mirror twin grain boundaries are characterized, and the influence of the grain boundaries on the material properties of molybdenum disulphide is assessed.

A hybrid quantum-classical algorithm for solving many-electron problems is developed, enabling the simulation, with the aid of 16 qubits on a quantum processor, of chemical systems with up to 120 orbitals.

The extent of problems in quantum chemistry for which quantum algorithms could provide a speedup is still unclear, as well as the kind of speedup one should expect. Here, the authors look at the problem of ground state energy estimation, and gather theoretical and numerical evidence for the fact that an exponential quantum advantage is unlikely for generic problems of interest.

A complete understanding of singlet fission (SF) in molecular materials will enable the design of optimised optoelectronic devices. Here, the authors use vacancy control in acene-based blends to link coherent and incoherent SF pathways to energetics.

Lead halide perovskites have unique electronic properties that depend on the crystal’s anharmonicity. Dielectric solvation theories, developed for molecules dissolved in polar liquids, are shown here to reproduce the temperature behavior of carrier solvation in the electronic spectra, implying strongly anharmonic lattice dynamics.

The transcription machinery must locate specific promoter sequences among a vast excess of nonspecific DNA. Real-time single-molecule experiments with E. coli RNA polymerase, combined with theoretical calculations, suggest that facilitated diffusion does not contribute to promoter targeting at physiologically relevant protein concentrations but that instead the promoter search is dominated by three-dimensional diffusion.

The trapping of interlayer valley excitons in a moiré potential formed by a molybdenum diselenide/tungsten diselenide heterobilayer with twist angle control is reported.

Computer simulations may unlock crucial aspects of how a liquid transforms into a glass, but are hampered by rapidly growing relaxation times near the transition. This Review summarizes progress towards overcoming this problem and creating realistic in silico glasses, and discusses what understanding has been enabled.