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Showing 1–3 of 3 results
Advanced filters: Author: Dominick C. Witkowski Clear advanced filters

  • Alkenes are essential functional groups in organic chemistry, featuring well-defined geometries and bond orders of 2. In this study, cubene and 1,7-quadricyclene are calculated to possess unusual hyperpyramidalized geometries and low alkene bond orders near 1.5. Their resultant high reactivities ultimately permit access to intricate scaffolds and new chemical space.

    • Jiaming Ding
    • Sarah A. French
    • Neil K. Garg
    ResearchOpen Access
    Nature Chemistry
    P: 1-10

  • The strained C6H6 isomer 1,2,3-cyclohexatriene and its derivatives participate in a host of reaction modes which demonstrate their potential for selective chemical transformations and provide an unconventional entryway to complex scaffolds.

    • Andrew V. Kelleghan
    • Ana S. Bulger
    • Neil K. Garg
    Research
    Nature
    Volume: 618, P: 748-754

  • Six-membered cyclic 1,2,3-trienes are geometrically distorted, short-lived intermediates that have high reactivity. Now, azacyclic 1,2,3-trienes can be generated and trapped, allowing for the synthesis of annulated pyridones.

    • Dominick C. Witkowski
    • Daniel W. Turner
    • Neil K. Garg
    Research
    Nature Synthesis
    Volume: 4, P: 1009-1016