Despite their importance as mechanistic models for Haber Bosch ammonia synthesis from N2 and H2, high oxidation state terminal metal-nitrides are notoriously unreactive towards H2. Here, the authors report hydrogenolysis of a uranium(V)-nitride, which can occur directly or by Frustrated Lewis Pair chemistry with a borane ancillary.
- Lucile Chatelain
- Elisa Louyriac
- Stephen T. Liddle
