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Showing 1–6 of 6 results
Advanced filters: Author: Gabriel dos Passos Gomes Clear advanced filters

  • Fluorinated poly(aryl thioethers), unlike their poly(aryl ethers) counterparts, have received little attention despite excellent physical properties displayed by many polysulfides. Here the authors show a highly efficient route to fluorinated poly(aryl thioethers) via an organocatalyzed nucleophilic aromatic substitution of silyl-protected dithiols.

    • Nathaniel H. Park
    • Gabriel dos Passos Gomes
    • James L. Hedrick
    ResearchOpen Access
    Nature Communications
    Volume: 8, P: 1-7

  • Predictably activating C–H and C–C bonds for the synthesis of new materials remains a challenge within the synthetic community. A ternary catalytic dance between radicals, metals and light may unlock this puzzle.

    • Thiago Reschützegger
    • Thomas Syphan
    • Gabriel dos Passos Gomes
    News & Views
    Nature Synthesis
    Volume: 1, P: 13-15

  • Constrained molecules typically adopt one major conformation and this limitation prevents the study of other energetically less-favourable conformations. Nevertheless, these alternate structures might prove to be useful and it has now been shown that a dominant rotor method can alter the energetic landscape of peptides to create two-well systems with distinct conformational behaviour.

    • Diego B. Diaz
    • Solomon D. Appavoo
    • Andrei K. Yudin
    Research
    Nature Chemistry
    Volume: 13, P: 218-225

  • Scientific understanding is one of the main aims of science. This Perspective discusses how advanced computational systems, and artificial intelligence in particular, can contribute to driving scientific understanding.

    • Mario Krenn
    • Robert Pollice
    • Alán Aspuru-Guzik
    Reviews
    Nature Reviews Physics
    Volume: 4, P: 761-769

  • An automated closed-loop system optimizes a stereoselective Suzuki-Miyaura reaction using a machine learning algorithm that incorporates unbiased and categorical process parameters.

    • Melodie Christensen
    • Lars P. E. Yunker
    • Jason E. Hein
    ResearchOpen Access
    Communications Chemistry
    Volume: 4, P: 1-12