We introduce a mechanism that can result in metallicity at stoichiometric interphase boundaries between semiconductors, based on the idea of polar catastrophe induced by charge density discontinuity. As an example, we demonstrate metallicity at the stoichiometric (110) interphase boundary of the semiconductors SnO and SnO2. The proposed mechanism is of general validity and expected to have an important role at interphase boundaries between polar materials.
- Arwa Albar
- Hassan Ali Tahini
- Udo Schwingenschlögl