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Showing 1–3 of 3 results
Advanced filters: Author: Hesham Alhumade Clear advanced filters

  • Ligands and additives are often utilized to stabilize low-valent catalytic metal species experimentally, while their role in suppressing metal deposition has been less studied. Here, the authors report an on-cycle mechanism for CoCl2bpy2 catalyzed Negishi-type cross-coupling describing a full catalytic cycle for this reaction using multiple spectroscopic studies.

    • Xu Luo
    • Dali Yang
    • Aiwen Lei
    ResearchOpen Access
    Nature Communications
    Volume: 14, P: 1-10

  • Anodic C(sp3)–H bond oxidative functionalization that involve C(sp3)–M, a C(sp3) radical or a C(sp3) cation intermediate with hydrogen evolution can be achieved by direct and indirect electrolysis. This Review discusses both strategies, and gives examples of the electrochemical methods developed for such functionalization reactions.

    • Zhaoliang Yang
    • Wenyan Shi
    • Aiwen Lei
    Reviews
    Nature Synthesis
    Volume: 2, P: 217-230